中国有色金属学报(英文版)2024,Vol.34Issue(3) :874-889.DOI:10.1016/S1003-6326(23)66440-4

Ti基块体非晶合金在酸性溶液中的腐蚀行为

Corrosion behavior of Ti-based bulk amorphous alloys in acidic solutions

杨靓 张浩然 张山 施志林 韦超 马明臻 刘日平
中国有色金属学报(英文版)2024,Vol.34Issue(3) :874-889.DOI:10.1016/S1003-6326(23)66440-4

Ti基块体非晶合金在酸性溶液中的腐蚀行为

Corrosion behavior of Ti-based bulk amorphous alloys in acidic solutions

杨靓 1张浩然 1张山 1施志林 1韦超 2马明臻 1刘日平1
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作者信息

  • 1. 燕山大学亚稳材料制备技术与科学国家重点实验室,秦皇岛 066004
  • 2. 燕山大学亚稳材料制备技术与科学国家重点实验室,秦皇岛 066004;燕山大学理学院,秦皇岛 066004
  • 折叠

摘要

研究Ti34.3Zr31.5Cu5Ni5.5Be23.7块体非晶合金在不同浓度HC1和H2SO4溶液中的腐蚀行为.电化学测试与扫描电子显微镜分析发现,在极化过程中,Cl-离子在HC1溶液中引发点蚀损伤,点蚀电位随溶液浓度的增大而降低,被腐蚀表面的损伤程度则与溶液浓度呈正相关.在H2SO4溶液中材料表面形成钝化膜,表现出良好的耐蚀性.X射线光电子能谱分析发现,随着HC1溶液浓度的增加,钝化膜的稳定性降低.通过浸泡实验得到4种材料的腐蚀速率.结果显示,Ti34.3Zr31.5Cu5Ni5.5Be23.7块体非晶合金在HC1溶液中的耐腐蚀性能最好,其腐蚀速率为7.22×10-3 mm/a,约为316L不锈钢腐蚀速率的1/1294.

Abstract

The corrosion behavior of the Ti34.3Zr31.5Cu5Ni5.5Be23.7 bulk amorphous alloy was investigatedin different concentrations of the HCl and H2SO4 solutions.Electrochemical testing and scanning electron microscopy analysis indicate that Cl-ions can cause pitting damage in the HCl solution during the polarization process,and the pitting potential decreases with increasing solution concentration.The degree of damage to the corroded surfaceis positively correlated with the solution concentration.A passive film forms in the H2SO4 solution,indicating good corrosion resistance.X-ray photoelectron spectroscopy shows that the stability of the passivated film decreases with increasing HCl solution concentration.The corrosion rates of the four materials were obtained by an immersion experiment in HC1 solution.The results reveal that Ti34.3Zr31.5Cu5Ni5.5Be23.7 bulk amorphous alloy has the best corrosion resistance,with a corrosion rate of 7.22×103 mm/a,which is approximately l/1294that of 316L stainless steel.

关键词

钛基块体非晶合金/酸性溶液/钝化膜/腐蚀行为/腐蚀速率

Key words

Ti-based bulk amorphous alloy/acidic solution/passive film/corrosion behavior/corrosion rate

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基金项目

国家自然科学基金(52071278)

国家自然科学基金(51827801)

国家重点研发计划(2018YFA0703603)

出版年

2024
中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCD
影响因子:1.183
ISSN:1003-6326
参考文献量35
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