首页|氨离子对水钴矿硫化浮选的影响及其机理

氨离子对水钴矿硫化浮选的影响及其机理

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引入氨离子强化主要的氧化钴矿物(水钴矿)的硫化,使其浮选回收率从不到20%显著提高到70%以上.微浮选和傅立叶变换红外分析表明,氨离子增强黄药的吸附强度,从而提高水钴矿的浮选回收率.Zeta电位、ICP-OES和XPS测试进一步表明,水钴矿表面的钴可通过形成氨配合物而转移到液相中,从而增加矿物表面的硫吸附位点,促进硫化.这项研究将有助于更好地理解水钴矿的浮选行为,并为高效回收氧化钴矿提供有价值的参考.
Effect of ammonia on sulfidization flotation of heterogenite and its mechanism
Ammonium ion was introduced to enhance the sulfidization of heterogenite,the main cobalt oxide mineral.The flotation recovery was significantly improved from less than 20%to over 70%.Micro flotation and FT-IR analyses indicated that ammonium ions enhanced the adsorption intensity of xanthate and improved the flotation recovery of heterogenite.Zeta potential,ICP-OES,and XPS tests further illustrated that cobalt on the surface of heterogenite was transferred to the liquid phase by forming ammonia complexes,thereby increasing the sulfur adsorption sites on the mineral surface and promoting sulfidization.This study will contribute to a better understanding of the flotation behavior of heterogenite and provide a valuable reference for the efficient recovery of cobalt oxide ores.

heterogeniteammonium activitysulfidization flotationcobalt oxide ore

张国范、高永强、王梦涛

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中南大学资源加工与生物工程学院,长沙 410083

中南大学战略含钙矿物清洁高效利用湖南省重点实验室,长沙 410083

水钴矿 氨离子活化 硫化浮选 氧化钴矿

国家重点研发计划

2022YFC2904601

2024

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCD
影响因子:1.183
ISSN:1003-6326
年,卷(期):2024.34(4)
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