中国有色金属学报(英文版)2024,Vol.34Issue(10) :3265-3281.DOI:10.1016/S1003-6326(24)66607-0

通过添加Cu51Zr14孕育剂颗粒承载的多层石墨烯提高Cu-11.9Al-2.5Mn形状记忆合金的综合性能

Improving comprehensive properties of Cu-11.9Al-2.5Mn shape memory alloy by adding multi-layer graphene carried by Cu51Zr14 inoculant particles

焦志娴 王清周 丁燕军 殷福星 徐超辉 韩翠红 范其香
中国有色金属学报(英文版)2024,Vol.34Issue(10) :3265-3281.DOI:10.1016/S1003-6326(24)66607-0

通过添加Cu51Zr14孕育剂颗粒承载的多层石墨烯提高Cu-11.9Al-2.5Mn形状记忆合金的综合性能

Improving comprehensive properties of Cu-11.9Al-2.5Mn shape memory alloy by adding multi-layer graphene carried by Cu51Zr14 inoculant particles

焦志娴 1王清周 2丁燕军 3殷福星 4徐超辉 5韩翠红 5范其香5
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作者信息

  • 1. 天津职业技术师范大学机械工程学院,天津 300222;河北工业大学材料科学与工程学院,天津市材料层状复合与界面控制技术重点实验室,天津 300130
  • 2. 河北工业大学材料科学与工程学院,天津市材料层状复合与界面控制技术重点实验室,天津 300130
  • 3. 中南大学材料科学与工程学院,长沙 410083
  • 4. 广东省科学院新材料研究所,广州 510651
  • 5. 天津职业技术师范大学机械工程学院,天津 300222
  • 折叠

摘要

为了提高Cu-11.9Al-2.5Mn形状记忆合金(SMA)的综合性能,通过制备多层石墨烯(MLG)-Cu51Zr14复合粉末冷压预制体,将MLG由Cu51Zr14孕育剂颗粒承载后添加并分散于该合金中.在所制备的新型MLG/Cu-Al-Mn复合材料中,碎片状或絮状的MLG与Cu-Al-Mn基体结合良好.MLG可以阻碍Cu-Al-Mn SMA晶粒的粗化,并在MLG/Cu-Al-Mn界面附近产生热失配位错.MLG/Cu-Al-Mn复合材料的阻尼和力学性能显著提高,当MLG的含量达到0.2%(质量分数)时,其最高室温阻尼为0.0558,抗拉强度为801.5 MPa,伸长率为10.8%,硬度为HV308.基于深入的显微组织观察,结合内耗理论以及金属的强韧化理论,对相关机理进行讨论.

Abstract

In order to improve the comprehensive properties of the Cu-11.9Al-2.5Mn shape memory alloy(SMA),multilayer graphene(MLG)carried by Cu51Zr14 inoculant particles was incorporated and dispersed into this alloy through preparing the preform of the cold-pressed MLG-Cu51Zr14 composite powders.In the resultant novel MLG/Cu-Al-Mn composites,MLG in fragmented or flocculent form has a good bonding with the Cu-Al-Mn matrix.MLG can prevent the coarsening of grains of the Cu-Al-Mn SMA and cause thermal mismatch dislocations near the MLG/Cu-Al-Mn interfaces.The damping and mechanical properties of the MLG/Cu-Al-Mn composites are significantly improved.When the content of MLG reaches 0.2 wt.%,the highest room temperature damping of 0.0558,tensile strength of 801.5 MPa,elongation of 10.8%,and hardness of HV 308 can be obtained.On the basis of in-depth observation of microstructures,combined with the theory of internal friction and strengthening and toughening theories of metals,the relevant mechanisms are discussed.

关键词

Cu-Al-Mn形状记忆合金/多层石墨烯(MLG)/显微组织/界面/阻尼/力学性能

Key words

Cu-Al-Mn shape memory alloy/multilayer graphene(MLG)/microstructure/interface/damping/mechanical properties

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基金项目

Natural Science Foundation of Hebei Province,China(E2021202017)

National Natural Science Foundation of China(52061038)

Foundation Strengthening Program,China(2019-JCJQ-ZD-142-00)

Hebei Province Graduate Innovation Funding Project,China(CXZZBS2022032)

Jiangsu Provincial Policy Guidance Program(Special Project for the Introduction of Foreign Talents)Talent Introduction Progr(BX2021024)

Science Plan Foundation of Tianjin Municipal Education Commission,China(2021KJ026)

出版年

2024
中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCD
影响因子:1.183
ISSN:1003-6326
参考文献量53
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