中国有色金属学报(英文版)2024,Vol.34Issue(10) :3295-3308.DOI:10.1016/S1003-6326(24)66609-4

铼及二氧化铈复合强化钼合金的力学性能

Enhanced mechanical properties of molybdenum alloy originating from composite strengthening of Re and CeO2

张梦瑶 马帅 李鑫 高野 吴壮志 王德志
中国有色金属学报(英文版)2024,Vol.34Issue(10) :3295-3308.DOI:10.1016/S1003-6326(24)66609-4

铼及二氧化铈复合强化钼合金的力学性能

Enhanced mechanical properties of molybdenum alloy originating from composite strengthening of Re and CeO2

张梦瑶 1马帅 1李鑫 1高野 1吴壮志 2王德志2
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作者信息

  • 1. 中南大学材料科学与工程学院,长沙 410083
  • 2. 中南大学材料科学与工程学院,长沙 410083;中南大学粉末冶金国家重点试验室,长沙 410083
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摘要

为了提高钼合金在常温及高温条件下的力学性能,采用粉末冶金方法制备Mo-14Re-1CeO2合金,并探究其微观结构和力学性能.结果表明,Mo-14Re-1CeO2的极限抗拉强度达到657 MPa,总伸长率为35.2%,明显高于纯钼(453 MPa、7.01%).另外,Mo-14Re-1CeO2在高温(1200 ℃)下的压缩强度达到355 MPa,同样高于纯钼(221 MPa).CeO2与Mo-14Re基体间形成共格界面,且CeO2颗粒均匀分布于晶界和晶内.该合金力学性能的提升主要归因于Mo-Re固溶体的形成、晶粒细化以及CeO2颗粒的弥散强化效应.

Abstract

To enhance the mechanical properties of molybdenum alloys at both room and high temperatures,Mo-14Re-1CeO2 alloy was synthesized using the powder metallurgy method,and the corresponding microstructure and mechanical properties were characterized.The results indicate that the ultimate tensile strength of Mo-14Re-1CeO2 reaches 657 MPa,with a total elongation of 35.2%,significantly higher than those of pure molybdenum(453 MPa,and 7.01%).Furthermore,the compression strength of Mo-14Re-1CeO2 at high temperature(1200 ℃)achieves 355 MPa,which is still larger than that of pure molybdenum(221 MPa).It is revealed that there is a coherent interface between CeO2 and the Mo-14Re matrix with CeO2 particles uniformly distributed in both intergranular and intragranular regions.The improvements in mechanical properties are primarily attributed to the formation of Mo-Re solid solution,grain refinement,and dispersion strengthening effect of CeO2.

关键词

钼铼合金/CeO2/复合强化/力学性能

Key words

molybdenum-rhenium alloy/cerium oxide/composite strengthening/mechanical properties

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基金项目

National Key R&D Program of China(2022YFB3705402)

出版年

2024
中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCD
影响因子:1.183
ISSN:1003-6326
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