中国有色金属学报(英文版)2024,Vol.34Issue(11) :3777-3788.DOI:10.1016/S1003-6326(24)66640-9

Fe2+溶蚀法清理阳极泥对Pb?0.6%Ag阳极电化学性能及锌电积的影响

Effects of anode slime removing by Fe2+dissolution method on electrochemical properties of Pb?0.6%Ag anode and zinc electrowinning

王文军 李澜波 刘旭 袁铁锤 高和欣
中国有色金属学报(英文版)2024,Vol.34Issue(11) :3777-3788.DOI:10.1016/S1003-6326(24)66640-9

Fe2+溶蚀法清理阳极泥对Pb?0.6%Ag阳极电化学性能及锌电积的影响

Effects of anode slime removing by Fe2+dissolution method on electrochemical properties of Pb?0.6%Ag anode and zinc electrowinning

王文军 1李澜波 2刘旭 3袁铁锤 2高和欣2
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作者信息

  • 1. 中南大学 粉末冶金国家重点实验室,长沙 410083;浙江力博实业股份有限公司,绍兴 312000;邵阳学院 机械与能源工程学院,邵阳422000
  • 2. 中南大学 粉末冶金国家重点实验室,长沙 410083
  • 3. 株洲冶炼集团股份有限公司,株洲 412000
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摘要

对比研究Fe2+溶蚀法和人工法清理阳极泥对铸造Pb−0.6%Ag(质量分数)阳极性能和锌电积的影响.结果表明,Fe2+溶蚀法能避免阳极表面氧化膜层受到机械损伤,而传统人工法无法实现,这将使阳极腐蚀速率降低57.14%,从而减少电解液和锌产品的Pb污染.同时,相较于人工法,Fe2+溶蚀法清理阳极泥可显著提高阳极的电催化活性,使阳极泥清理后的锌电积初始电耗低至2720 kW·h/t.

Abstract

Fe2+dissolution method and manual method were used to remove the anode slime and their effects on properties of cast Pb−0.6wt.%Ag anode and zinc electrowinning were compared. The results reveal that the Fe2+dissolution method can avoid mechanical damage to the oxide film layer on the anode surface,which cannot be achieved by traditional manual method. This can lower the anode corrosion rate by 57.14%,thus reducing Pb contamination in electrolyte and zinc products. Meanwhile,compared with manual method,Fe2+dissolution method can significantly improve the electrocatalytic activity of the anode and lower the initial power consumption of zinc electrowinning to 2720 kW·h/t after removing anode slime.

关键词

Pb−Ag阳极/锌电积/阳极泥清理/电化学性能

Key words

Pb−Ag anode/zinc electrowinning/anode slime removing/electrochemical properties

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出版年

2024
中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCD
影响因子:1.183
ISSN:1003-6326
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