首页|不同固溶处理对Cu-Cr系合金组织和性能的影响

不同固溶处理对Cu-Cr系合金组织和性能的影响

Effect of different solid solution treatments on microstructure and properties of Cu-Cr alloy

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热处理工艺调控是提升Cu-Cr系合金性能的有效方法.Cu-Cr系合金的固溶工艺大多选择温度较低的Cu-Cr两相区进行,导致Cr相固溶程度不完全,抑制后续析出强化效果.本研究提出采用高温单相区固溶工艺改善析出强化效果,主要研究不同固溶工艺(Cu-Cr两相区(950℃,4 h)和Cu单相区(1050℃,6 h))对Cu-Cr系合金组织和性能的影响.采用电子探针(EPMA)对两种固溶工艺后的元素分布进行表征,并对峰值时效态合金的微观结构采用XRD和TEM进行表征分析.结果表明:与两相区固溶相比,单相区固溶后铸态Cr相充分固溶,时效过程中更多纳米Cr相弥散析出;合金力学性能相比两相区固溶后峰值时效态有较大提升,其中屈服强度提升29.3%,抗拉强度提升25.6%,而导电率并未明显下降.强度理论计算结果表明,析出强化所贡献的屈服强度增量为323.4 MPa,贡献56.9%,析出强化是本研究中最主要的强化机制.
Heat treatment is well-known to be effective to improve the performance of Cu-Cr alloys.The solid solution process of Cu-Cr alloys mostly selects the lower temperature Cu-Cr two-phase region,resulting in incomplete dissolution of Cr phase and inhibiting subsequent precipitation strengthening effect.A high-temperature single-phase region solid solution process was proposed to improve the strengthening effect.The effects of different solid solution processes((950℃,4 h)in the two-phase region and(1050℃,6 h)in the single-phase region)on the microstructure and properties of Cu-Cr alloy were comparably studied.The element distribution after two solid solution processes was characterized by electron probe microanalyzer(EPMA),and the microstructure of the peak-aged alloy was characterized and analyzed by XRD and TEM.The results show that,compared with solid solution in the two-phase region,the cast Cr phase is fully dissolved after solid solution in the single-phase region,and more nano Cr phases precipitate during aging.The mechanical properties of the alloy are significantly improved compared to those of the alloy at the peak-aged state after solid solution in the two-phase region,the yield strength increases by 29.3%and tensile strength increases by 25.6%,while the electrical conductivity does not decrease significantly.Strength theory calculations results indicate that the yield strength increment contributed by precipitation strengthening is 323.4 MPa,accounting for 56.9%,which is the most significant strengthening mechanism in this study.

Cu-Cr alloysolid solution in single-phase regionprecipitation strengtheningelectrical conductivity

杨旗、王志磊、肖星宇、谢建新

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北京科技大学 新材料技术研究院 现代交通金属材料与加工技术北京实验室,北京 100083

北京科技大学 新材料技术研究院 材料先进制备技术教育部重点实验室,北京 100083

辽宁材料实验室 材料智能技术研究所,沈阳 110004

Cu-Cr合金 单相区固溶 析出强化 导电率

国家重点研发计划资助项目

2021YFB3803100

2024

中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCD北大核心
影响因子:1.108
ISSN:1004-0609
年,卷(期):2024.34(1)
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