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超声预处理对锂辉石矿物浮选分离的影响

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采用NaOH溶蚀与超声波耦合机械搅拌相结合的预处理技术对锂辉石、石英和长石进行浮选前预处理,以探究超声预处理对锂辉石矿物浮选分离的影响.通过开展单矿物浮选和人工混合矿浮选试验,比较超声波耦合机械搅拌与传统机械搅拌两种预处理技术的优缺点;为了探明预处理技术的作用机理,对经不同预处理后的矿样进行了SEM、吸附量测试和XPS分析.结果表明:超声预处理后,锂辉石与长石、石英之间的可浮性差异进一步增大,-0.074+0.038 mm粒级的锂辉石人工混合矿精矿浮选回收率最高可达48.23%,分选效率达到44.27%;相较于传统机械搅拌预处理,超声波耦合机械搅拌预处理的浮选效果进一步提高.介入超声波预处理后可进一步改变锂辉石矿物表面形貌,并促进更大范围的表面溶蚀,从而增加矿物表面药剂吸附,且超声波耦合机械搅拌预处理后的锂辉石比传统机械搅拌预处理后的锂辉石具有更强的NaOL吸附能力,可见超声预处理技术对锂辉石、石英和长石的浮选分离具有显著的促进作用.
Effect of ultrasonic pretreatment on flotation saparation of spodumene ore
This article describes a pretreatment technique using a combination of NaOH dissolution and ultrasound-coupled mechanical stirring to investigate the effect of ultrasound pretreatment on the flotation separation of lithium spodumene,quartz and feldspar minerals.By conducting single mineral flotation experiments and artificial mixed mineral flotation experiments,the excellent the ultrasound-coupled mechanical stirring pretreatment was compared with that of the traditional mechanical stirring pretreatment.To explore the mechanism of pretreatment technology,SEM,adsorption test and XPS analysis were conducted on samples treated with different pretreatment methods.The results indicate that,the floatability difference between spodumene,feldspar and quartz increases further after ultrasonic pretreatment.The recovery rate of spodumene concentrate from artificial mixed mineral flotation with a particle size of-0.074+0.038 mm can reach up to 48.23%,and the separation efficiency can reach 44.27%.Compared with traditional mechanical stirring pretreatment,the flotation effect of ultrasound-coupled mechanical stirring pretreatment is further improved.In order to explore the mechanism of the pretreatment technology,SEM,adsorption capacity test and XPS detection analysis were conducted on the ore samples.The analysis results indicate that intervention with ultrasound pretreatment can further change the surface morphology of spodumene minerals and promote a greater range of surface dissolution,thereby increasing the adsorption of reagents on mineral surfaces.Moreover,spodumene treated with ultrasound-coupled mechanical stirring pretreatment exhibits stronger NaOL adsorption capacity compared to spodumene treated with traditional mechanical stirring pretreatment.Overall,the experimental results suggest that ultrasound pretreatment has a significant promoting effect on the flotation separation of spodumene,quartz and feldspar.

spodumeneflotationultrasoundpretreatmentselective dissolution

张宇新、陈兰兰、褚浩然、卢东方、王毓华

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中南大学 资源加工与生物工程学院,长沙 410083

锂辉石 浮选 超声波 预处理 选择性溶蚀

国家重点研发计划国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金

2021YFC290320252174270521742675197436651674290

2024

中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCD北大核心
影响因子:1.108
ISSN:1004-0609
年,卷(期):2024.34(2)
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