中国有色金属学报2024,Vol.34Issue(5) :1453-1474.DOI:10.11817/j.ysxb.1004.0609.2023-44510

碳/铝复合材料界面Al4C3相的形成与调控研究进展

Reviews on formation and tailoring of interfacial Al4C3 phase in carbon/aluminum composites

李肖亮 李昱桦 董正学 万梓涵 任可聪 邓海亮 杨康 吴操
中国有色金属学报2024,Vol.34Issue(5) :1453-1474.DOI:10.11817/j.ysxb.1004.0609.2023-44510

碳/铝复合材料界面Al4C3相的形成与调控研究进展

Reviews on formation and tailoring of interfacial Al4C3 phase in carbon/aluminum composites

李肖亮 1李昱桦 2董正学 3万梓涵 3任可聪 3邓海亮 1杨康 3吴操3
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作者信息

  • 1. 安徽工业大学 先进金属材料绿色制备与表面技术教育部重点实验室,马鞍山 243002;安徽工业大学 材料科学与工程学院先进陶瓷研究中心,马鞍山 243002
  • 2. 四川航天天盛装备科技有限公司,成都 610100
  • 3. 安徽工业大学 材料科学与工程学院先进陶瓷研究中心,马鞍山 243002
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摘要

石墨烯、碳纳米管和碳纤维等碳材料作为铝基复合材料的增强体时,其界面润湿性差、与Al基体结合弱等缺点限制了其增强效果.利用C与Al反应使界面黏接形式转变为部分反应结合的形式,可有效提升碳/铝(C/Al)界面强度及其载荷与功能传递的效率.然而,高温下C/Al界面反应易生成大量脆性Al4C3,且会损伤增强体.针对C/Al界面Al4C3的调控,本文首先介绍了其形成机制、对C/Al复合材料界面结合和性能的作用,随后从碳增强体表面涂层、纳米颗粒修饰、Al基体合金化,以及复合制备、热加工与处理工艺优化等方面,综述了Al4C3生成量与形貌的控制研究及效果,最后展望了C/Al复合材料界面与性能的研究方向,以期通过碳增强体跨尺度设计与界面构型控制,挖掘石墨烯、碳纳米管和碳纤维增强Al基体的最大潜能.

Abstract

Graphene,carbon nanotube,and carbon fiber applied as reinforcements have poor wettability and weak bonding with aluminum matrix,which limit the function utilization of these carbon materials.The reaction between carbon and aluminum transforms the bonding of carbon/aluminum interface into partial reaction bonding,thereby enhance availably the interface strength and its efficiency of load and function transfers.Unfortunately,a large amount of brittle Al4C3 is readily formed by the interface reaction under high temperatures,leading to obvious damages of the carbon reinforcements.Aiming the tailoring of Al4C3 phase,the nucleation and growth mechanisms of Al4C3 and its effects on the interface bonding and performance of carbon/aluminum composites were introduced in this paper.Subsequently,the studies on the tailoring of Al4C3 amount and morphology,and the achieved results were reviewed from the aspects such as surface coating and nanoparticle decoration of carbon reinforcements,alloying of aluminum matrix,and optimizations of fabrication,hot working and treatment processes.The investigation focuses on the interface and performance of the composites were proposed finally.The maximum reinforcing potentials of graphene,carbon nanotube,and carbon fiber on aluminum matrix would be explored via multi-scaled designing of these carbon reinforcements and tailoring of the interface configurations.

关键词

铝基复合材料/石墨烯/碳纳米管/碳纤维/Al4C3相

Key words

aluminum matrix composites/graphene/carbon nanotube/carbon fiber/Al4C3 phase

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基金项目

国家自然科学基金(51972002)

国家自然科学基金(52102372)

国家自然科学基金(52372019)

安徽省高等学校自然科学研究项目(KJ2021ZD0040)

出版年

2024
中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCD北大核心
影响因子:1.108
ISSN:1004-0609
参考文献量17
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