中国有色金属学报2024,Vol.34Issue(5) :1712-1726.DOI:10.11817/j.ysxb.1004.0609.2023-44601

酸浸米糠协同脱硫石膏驱动赤泥成土

Synergistic effects of acid-treated rice bran and desulfurization gypsum on soil formation of bauxite residue

黄诗蔚 张子颖 钟小琳 江钧 朱锋 蒋逸凡 张雨菲 薛生国
中国有色金属学报2024,Vol.34Issue(5) :1712-1726.DOI:10.11817/j.ysxb.1004.0609.2023-44601

酸浸米糠协同脱硫石膏驱动赤泥成土

Synergistic effects of acid-treated rice bran and desulfurization gypsum on soil formation of bauxite residue

黄诗蔚 1张子颖 1钟小琳 1江钧 2朱锋 2蒋逸凡 1张雨菲 1薛生国2
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作者信息

  • 1. 中南大学 冶金与环境学院,长沙 410083
  • 2. 中南大学 冶金与环境学院,长沙 410083;国家重金属污染防治工程技术研究中心,长沙 410083
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摘要

赤泥土壤化是降低赤泥环境风险、实现规模化消纳的可行方法.本研究通过植酸酸浸溶出的方法,探究米糠酸浸出液和浸出渣协同脱硫石膏对赤泥成土过程的影响.结果表明:联合施用酸浸米糠(2%)和脱硫石膏(2%)30 d后,赤泥的pH和电导率(γ)分别从10.56和169.67 μS/cm降低至8.42和75.53 μS/cm,Na2O含量降低,大团聚体比例、非毛管孔隙度均升高,总有机碳(TOC)、有效磷(AP)含量增加,黑麦草生长状况良好;Al3+、Fe3+、Ca2+和Mg2+与植酸形成不溶性螯合物,植物受到的阳离子胁迫明显缓解;添加脱硫石膏可降低米糠施用量,Ca2+能加快脱碱效率、促进植酸盐分解,提高TOC和AP含量.

Abstract

Soil formation of bauxite residue is the valid way to reduce the environmental risk and large-scale consumption.The present study investigated the effects of leaching solution and leachate from acid-treated rice bran synergized with desulfurization gypsum on soil formation of bauxite residue using an acid leaching method with phytic acid.The results show that the pH and EC of the bauxite residue decrease from 10.56 and 169.67 μS/cm to 8.42 and 75.53 μS/cm,respectively,after treatment by acid-treated rice bran(2%)and desulfurization gypsum(2%)for 30 d.The content of Na2O in alkaline mineral also decreases,while the proportion of large aggregates,non-capillary porosity,total organic carbon(TOC),and available phosphorus(AP)increases.Furthermore,the growth of ryegrass is improved.Cations of Al3+,Fe3+,Ca2+and Mg2+form insoluble chelates with phytic acid,thereby obviously reducing the cationic stress of plants.The Ca2+cation dissolved from desulfurization gypsum can accelerate the dealkalization efficiency,promote phytate decomposition,and increase TOC and AP contents while reduce the addition of rice bran.

关键词

赤泥/酸浸米糠/脱硫石膏/植酸/绿化种植土

Key words

bauxite residue/acid-treated rice bran/desulfurization gypsum/phytic acid/planting soil for greening

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基金项目

国家自然科学基金(42177391)

国家自然科学基金(42077379)

国家自然科学基金(42030711)

国家重点研发计划(2019YFC1803604)

中南大学创新驱动项目(2023CXQD065)

出版年

2024
中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCD北大核心
影响因子:1.108
ISSN:1004-0609
参考文献量9
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