中国有色金属学报2024,Vol.34Issue(10) :3209-3227.DOI:10.11817/j.ysxb.1004.0609.2024-44742

相变与变形中的约束

Constraints in phase transformation and deformation

贾东昇 吴盼 于斐涵 刘峰
中国有色金属学报2024,Vol.34Issue(10) :3209-3227.DOI:10.11817/j.ysxb.1004.0609.2024-44742

相变与变形中的约束

Constraints in phase transformation and deformation

贾东昇 1吴盼 1于斐涵 1刘峰2
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作者信息

  • 1. 西北工业大学 凝固技术国家重点实验室,西安 710072
  • 2. 西北工业大学 凝固技术国家重点实验室,西安 710072;西北工业大学 分析测试中心,西安 710072
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摘要

材料加工与成形涉及的相变和变形中,由于热力学或热-动力学变化而产生的使相变/变形发生与发展的物理作用可定义为约束.本文面向微观组织的形成与变形过程,立足于笔者近年来提出的关于热力学稳定性和广义稳定性、热-动力学相关性和热-动力学配分的材料设计理论框架,明确了热力学约束和热-动力学约束的表现形式和作用机制.热力学约束代表相变/变形启动的难易程度,而热-动力学约束从能量变化而言,体现为形核约束长大和长大约束形核,从过程快慢而言,则体现为热力学约束动力学和动力学约束热力学.本文选择代表性相变或变形过程,定量描述了上述约束,基于此,提出主动设计约束的学术理念,旨在通过定量设计材料加工过程而获取力学性能优异的金属结构材料.

Abstract

Upon phase transformations and plastic deformations involved in material processing and forming,so-called constraints can be defined as physical effects that initiate and develop arising from thermodynamic or thermo-kinetic evolution.Aiming for the formation and deformation of metallic microstructure,the thermodynamic and the thermo-kinetic constraints were herein clarified based on the theoretical framework of material design including thermodynamic stability,generalized stability,thermo-kinetic correlation and thermo-kinetic partition proposed by the current author in recent years.The thermodynamic constraint represented how easy it is for the phase transformation/deformation to be initiated,while the thermo-kinetic constraint was reflected by the nucleation constraint growth and the growth constraint nucleation in terms of the energy change,and by the thermodynamic constraint kinetics and kinetic constraint thermodynamics in terms of progressing transformation.In this paper,representative phase transformations or deformation processes were selected to quantitatively describe the above constraints,and then,an academic concept was proposed to design the constraints artificially and intentionally,to obtain structured materials with excellent mechanical properties through the quantitative design of material processing processes.

关键词

热力学/动力学/相变/变形/约束

Key words

thermodynamics/kinetics/phase transformation/deformation/constraint

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基金项目

国家自然科学基金资助项目(52130110)

国家自然科学基金资助项目(52271116)

国家自然科学基金资助项目(52431002)

出版年

2024
中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCDCSCD北大核心
影响因子:1.108
ISSN:1004-0609
参考文献量131
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