中国有色金属学报2024,Vol.34Issue(11) :3634-3642.DOI:10.11817/j.ysxb.1004.0609.2024-45026

基于脱合金反应制备富Nb相增强非晶复合材料的微观组织与力学性能

Microstructure and mechanical property of Nb-rich phase reinforced amorphous alloy matrix composites via dealloying reaction in metallic melt

郭威 祝梦媛 赵觅 吕书林 吴树森
中国有色金属学报2024,Vol.34Issue(11) :3634-3642.DOI:10.11817/j.ysxb.1004.0609.2024-45026

基于脱合金反应制备富Nb相增强非晶复合材料的微观组织与力学性能

Microstructure and mechanical property of Nb-rich phase reinforced amorphous alloy matrix composites via dealloying reaction in metallic melt

郭威 1祝梦媛 1赵觅 2吕书林 1吴树森1
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作者信息

  • 1. 华中科技大学材料科学与工程学院,材料成形与模具技术全国重点实验室,武汉 430074
  • 2. 华中科技大学 航空航天学院,武汉 430074;深圳华中科技大学研究院,深圳 518057
  • 折叠

摘要

本文采用传统电弧熔炼与金属熔体脱合金法两种手段成功制备了富Nb相增强锆基非晶复合材料,并系统比较了上述两种方法制备获得的样品的微观组织和力学性能.结果表明:基于电弧熔炼与熔体脱合金工艺均可获得富Nb相增强非晶复合结构,无杂质析出相生成,样品热学特征值相近.但是,利用金属熔体脱合金反应制备获得的非晶复合组织中富Nb相尺寸更小,综合力学性能相比于传统电弧熔化法更加优异.因此,形变过程中富Nb相可有效阻碍基体中主剪切带的迅速扩展,促进剪切带增殖,形成多重剪切带.同时,富Nb相本身塑性变形也可进一步降低其界面应力水平,提高材料的强韧性.

Abstract

The Nb-rich phase reinforced Zr-based amorphous alloy matrix composites were successfully fabricated via both conventional arc-melting and dealloying in metallic melt approaches.The microstructure and mechanical property of these samples fabricated by different methods were symmetrically compared.The results show that Nb-rich phase reinforced amorphous alloy matrix composite structure without any unexpected precipitations can be obtained by both methods,and the thermal property of these samples are similar.However,the Nb-rich phase in the samples fabricated by dealloying reactions is much finer than those by arc-melting,and the subsequent mechanical property is improved for the former samples.The Nb-rich phase can effectively hinder the rapid propagation of shear bands during the deformation,causing the multiplication of it to generate multiple shear bands.Meanwhile,the plastic deformation of Nb-rich phase itself can further decrease the degree of stress concentration at the interface to improve the plasticity of the composites.

关键词

非晶复合材料/脱合金反应/微观组织/强韧性

Key words

amorphous alloy matrix composite/dealloying reaction in metallic melt/microstructure/strengthening and toughening

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出版年

2024
中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCDCSCD北大核心
影响因子:1.108
ISSN:1004-0609
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