首页|退役锂离子电池正极材料的直接修复:研究进展、挑战和展望

退役锂离子电池正极材料的直接修复:研究进展、挑战和展望

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伴随着新能源产业快速发展,锂离子电池生产量急剧增加.因为其有限的使用寿命,未来将迎来锂离子电池退役高峰.高效清洁回收退役锂离子电池,打通新能源产业链的最后一环,对于新能源产业的闭环发展至关重要.目前,针对退役的锂离子电池正极材料主要采用固相法(固相烧结、熔盐法等)以及液相法(水热法、电化学法等)进行直接再生.本文从退役锂离子电池的修复方法出发,简述了其前处理工艺与修复过程的关联,重点阐述了修复方法对于退役正极材料的晶相、缺陷、表界面以及电化学性能等方面的影响.最后,针对退役材料的直接修复方法,进行系列展望,旨在为退役锂离子电池正极材料未来直接修复技术提供有意义的指导.
Direct regeneration of spent cathode materials for lithium-ion batteries:Research advances,challenges and prospects
With the rapid development of the new energy industry,the production of lithium-ion batteries has increased sharply. Due to its limited life,the peak of lithium-ion battery retirement will come in the future. Efficient and clean recycling of spent lithium-ion batteries is the last link of the new energy industry chain. The step is crucial to the closed-loop development of the new energy industry. At present,the cathode materials of spent lithium-ion batteries are mainly directly recycled by solid phase method (solid phase sintering,molten salt method,etc.) and liquid phase method (hydrothermal method,electrochemical method,etc.). In this paper,the relationship between the pre-treatment process and the repair process of spent lithium-ion batteries is briefly described,and the influence of the repair method on the crystal phase,defects,surface interface and electrochemical properties of the spent cathode materials is emphasized. Finally,a series of prospects for the direct repair methods of spent lithium-ion battery materials are presented,aiming at providing meaningful guidance for the future direct repair technology of spent lithium-ion battery cathode materials.

lithium-ion batteriesspent cathode materialdirect regeneration methodselectrochemical performance

鲁向锦、曾子豪、袁正巧、王彬、雷海、杨越、葛鹏、孙伟

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中南大学资源加工与生物工程学院,长沙 410083

锂离子电池 退役正极材料 直接再生方法 电化学性能

2024

中国有色金属学报
中国有色金属学会

中国有色金属学报

CSTPCD北大核心
影响因子:1.108
ISSN:1004-0609
年,卷(期):2024.34(12)