首页|高韧性3D打印光敏树脂制备及性能研究

高韧性3D打印光敏树脂制备及性能研究

Preparation and Performance Study of High Toughness 3D Printing Photosensitive Resin

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数字光处理(DLP)打印技术在各种3D打印技术中具有明显优势,高性能、高韧性的DLP打印用光敏树脂具有巨大的市场需求.本研究针对光敏树脂固化过程中的水平尺寸稳定性,设计了一种测试方法,探究了单体、预聚物种类、引发剂含量、光固化时间等因素对树脂水平尺寸稳定性的影响,得到了树脂水平尺寸最佳稳定性的参数.然后制备出了适合DLP打印技术的柔性和刚性光敏树脂,将两种树脂按一定比例混合,测试了打印样品的拉伸强度等力学特性,对样品拉伸断裂面进行了扫描电镜分析,研究了树脂组分对材料韧性的影响.结果表明,将刚性光敏树脂作为连续相,提供弹性模量,将柔性光敏树脂作为分散相,提供应力集中物,二者分别以3∶1、1∶1的质量比混合,能够大幅提高打印材料的韧性和断裂伸长率.
Digital Light Processing(DLP)printing technology has obvious advantages in various 3D printing technologies,and there is a huge market demand for high-performance and high toughness photosensitive resins for DLP printing.This study designed a testing method for the horizontal dimension stability of photosensitive resin during the curing process and the effects of factors such as monomer,prepolymer type,initiator content,and curing time on the horizontal dimension stability of the resin were investigated.The flexible and rigid photosensitive resins suitable for DLP printing technology were prepared using this testing method.The two resins were mixed in a certain proportion,and the mechanical properties such as the tensile strength of the printed sample were tested.The tensile fracture surfaces of the samples were analyzed by scanning electron microscopy,and the effect of resin components on material toughness was studied.The results showed that using rigid photosensitive resin as a continuous phase,provides elastic modulus,and using flexible photosensitive resin as a dispersed phase,provides stress concentration.The two resins are mixed in a ratio of 3∶1 and 1∶1,which can significantly improve the toughness and elongation at break of printing materials.

3D printingPhotosensitive resinHigh toughnessDimension stability

刘创纪、徐英杰、黄蓓青、赵星宇、王雨欣

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北京印刷学院 印刷与包装工程学院,北京 102600

3D打印 光敏树脂 高韧性 尺寸稳定性

北京印刷学院校级青年卓越项目教改创新重点项目国家自然科学基金项目

Eb2023012215022306651802022

2024

数字印刷
中国印刷科学技术研究所

数字印刷

北大核心
ISSN:2095-9540
年,卷(期):2024.(3)