中国资源综合利用2024,Vol.42Issue(1) :9-12,18.DOI:10.3969/j.issn.1008-9500.2024.003

氯化液的海绵铜回收试验研究

Experimental Study on Sponge Copper Recovery from Chlorination Solution

胡磊 梁新星 郭持皓 孙贯永 梁东东
中国资源综合利用2024,Vol.42Issue(1) :9-12,18.DOI:10.3969/j.issn.1008-9500.2024.003

氯化液的海绵铜回收试验研究

Experimental Study on Sponge Copper Recovery from Chlorination Solution

胡磊 1梁新星 2郭持皓 1孙贯永 1梁东东1
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作者信息

  • 1. 矿冶科技集团有限公司,北京 100160
  • 2. 北方矿业有限责任公司,北京 100053
  • 折叠

摘要

本文采用石灰乳沉淀-铁粉置换法从氯化液中回收海绵铜,获得较好的效果.试验结果表明,Ca(OH)2 乳液浓度为 20%,沉淀反应pH=0,沉淀时间为 3 h,置换时间为 3 h,终点pH=0.42 时,小型试验获得的产品海绵铜纯度为 91.8%,二次滤液Cu浓度为 4.13 mg/L;中间试验获得的产品海绵铜纯度为88.2%,二次滤液Cu浓度为 15.1 mg/L.结果显示,产品海绵铜纯度均超过 88%,Cu基本全部被置换,中间试验指标略低于小型试验指标.该工艺切实可行,达到预期.

Abstract

This paper uses the lime milk precipitation-iron powder replacement method to recover sponge copper from chlorinated solution,achieving good results.The test results show that when the concentration of Ca(OH)2 lotion is 20%,the precipitation reaction pH=0,the precipitation time is 3 h,the replacement time is 3 h,and the end point pH=0.42,the purity of sponge copper obtained in the small-scale test is 91.8%,and the concentration of secondary filtrate Cu is 4.13 mg/L;the purity of sponge copper obtained from the intermediate test is 88.2%,and the concentration of Cu in the secondary filtrate is 15.1 mg/L.The results show that the purity of sponge copper in the product exceeds 88%,and almost all Cu is replaced,and the intermediate test indicators are slightly lower than the small-scale test indicators.This process is feasible and meets expectations.

关键词

石灰乳沉淀/铁粉置换/氯化液/海绵铜

Key words

lime milk precipitation/iron powder replacement/chlorination solution/sponge copper

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基金项目

矿冶科技集团基金资助项目(YJT2017012)

出版年

2024
中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
参考文献量12
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