首页|金属催化剂在电催化CO2还原反应中的应用

金属催化剂在电催化CO2还原反应中的应用

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在碳达峰碳中和(简称双碳)背景下,发展高效的CO2 转化技术已迫在眉睫.电催化还原CO2 是一种有效的CO2 转化方法,近年来发展迅猛,此法可以通过调节施加电位、催化剂、电解池、电解液等反应条件来调整反应进程和产物分布,具有清洁、高效、易调控的特点.本文立足于电催化还原CO2 方面的研究成果,简述电催化还原CO2 的反应原理,综述金属催化剂对还原产物选择性和产率的研究进展,介绍贵金属基催化剂、非贵金属基催化剂的不同结构与组成对电催化还原CO2 的影响,包括活性、选择性、稳定性等,并对电催化还原CO2 催化剂的发展方向进行展望,以更好地将金属催化剂应用在电催化CO2 还原反应中.
Application of Metal Catalysts in Electrocatalytic CO2 Reduction Reaction
In the context of carbon peak and carbon neutrality(referred to as dual carbon),it is urgent to develop efficient CO2 conversion technologies.Electrocatalytic reduction of CO2 is an effective CO2 conversion method that has developed rapidly in recent years,this method can adjust the reaction process and product distribution by adjusting reaction conditions such as applied potential,catalyst,electrolytic cell,and electrolyte,it has the characteristics of cleanliness,efficiency,and easy regulation.Based on the research achievements in electrocatalytic reduction of CO2,this paper briefly describes the reaction principle of electrocatalytic reduction of CO2,reviews the research progress of metal catalysts on the selectivity and yield of reduction products,introduces the influence of different structures and compositions of precious metal based catalysts and non precious metal based catalysts on electrocatalytic reduction of CO2,including activity,selectivity,stability,etc.,and looks forward to the development direction of electrocatalytic reduction of CO2 catalysts,so as to better apply metal catalysts in electrocatalytic CO2 reduction reactions.

carbon dioxideelectrocatalysismetalselectivity

鲁佩芳、阮少军

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徐州市环境监测中心

空军勤务学院,江苏 徐州 221000

二氧化碳 电催化 金属 选择性

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(2)
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