首页|低品位废料中回收铂和铑的工艺研究

低品位废料中回收铂和铑的工艺研究

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玻璃纤维厂产出的废耐火砖经选矿回收后,尾矿仍含有一定量的铂和铑。试验对尾矿进行加压酸浸处理,以期从低品位废料中回收铂和铑。在最佳浸出工艺条件下,耐火砖用量为 100 g,液固比为 5∶1,硫酸用量为 55 g,氯化钠用量为 40 g,硝酸钠用量为 25 g,反应温度为 200℃,系统压强为 1。6 MPa,反应时间为 4 h,铂的浸出率可达 66。51%,铑的浸出率可达 57。69%。试验结果表明,采用氯化钠+硝酸钠+硫酸体系处理该类型低品位废料,可实现铂和铑的高效浸出,该工艺具有较好的应用前景。
Research on the Process of Recovering Platinum and Rhodium from Low-Grade Waste
After the waste refractory bricks produced by the fiberglass factory are recycled through beneficiation,the tailings still contain a certain amount of platinum and rhodium.Experiments are conducted on pressurized acid leaching of tailings to recover platinum and rhodium from low-grade waste.Under the optimal leaching process conditions,the amount of refractory brick is 100 g,the liquid-solid ratio is 5∶1,the amount of sulfuric acid is 55 g,the amount of sodium chloride is 40 g,the amount of sodium nitrate is 25 g,the reaction temperature is 200℃,the system pressure is 1.6 MPa,and the reaction time is 4 h,the leaching rate of platinum can reach 66.51%,and the leaching rate of rhodium can reach 57.69%.The experimental results show that using a system of sodium chloride+sodium nitrate+sulfuric acid to treat this type of low-grade waste can achieve efficient leaching of platinum and rhodium,and this process has good application prospects.

low-grade wasteplatinumrhodiumrecyclingrefractory brickstailingspressure leaching

张帆、王芳、解雪、李梅、闫珂

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江苏北矿金属循环利用科技有限公司,江苏 徐州 221006

低品位废料 回收 耐火砖 尾矿 加压浸出

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(4)
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