首页|褐铁矿型和蛇纹石型红土镍矿提取镍钴的工艺研究

褐铁矿型和蛇纹石型红土镍矿提取镍钴的工艺研究

扫码查看
红土镍矿成分复杂,镍与钴的含量较低,主要类型有褐铁矿型和蛇纹石型。试验采用不同工艺对两种红土镍矿进行浸出,从而提取镍和钴。褐铁矿型红土镍矿采用拌酸熟化-水浸工艺进行处理。试验结果表明,当硫酸和红土镍矿的质量比为 1。84 时,镍与钴的浸出率均超过 97%,酸度越高,镍与钴的浸出率也越高;不管是先拌酸熟化再浸出,还是直接浆化加酸浸出,对镍与钴的浸出率影响不明显;在浸出过程中,添加还原剂,可使钴浸出率超过 96%,还原剂的加入有利于钴的浸出,但对镍的浸出影响不大。蛇纹石型红土镍矿则采用常压预浸-加压浸出工艺进行处理。试验结果表明,当总酸矿比为 0。53~0。58 t/t矿时,镍与钴的浸出率均超过 74%,加压浸出液的铁含量约为 5 g/L,残酸含量为 15~21 g/L。
Study on the Extraction Process of Nickel and Cobalt from Limonite Type and Serpentinite Type Laterite Nickel Ores
The composition of laterite nickel ore is complex,with low nickel and cobalt content,the main types are limonite type and serpentinite type.The experiment uses different processes to leach two types of laterite nickel ores,in order to extract nickel and cobalt.The limonite type laterite nickel ore is treated using a mixed acid maturation-water leaching process.The experimental results show that when the mass ratio of sulfuric acid to laterite nickel ore is 1.84,the leaching rates of nickel and cobalt both exceed 97%,and the higher the acidity,the higher the leaching rates of nickel and cobalt;whether it is mixed acid maturation before leaching or direct pulping and acid leaching,the effect on the leaching rate of nickel and cobalt is not significant;during the leaching process,adding a reducing agent can increase the cobalt leaching rate to over 96%,and the addition of a reducing agent is beneficial for cobalt leaching,but has little effect on nickel leaching.Serpentinite type laterite nickel ore is treated using the atmospheric pressure preleaching-pressurized leaching process.The experimental results show that when the total acid ore ratio is 0.53~0.58 t/t ore,the leaching rates of nickel and cobalt both exceed 74%,at this time,the iron content of the pressurized leaching solution is about 5 g/L,and the residual acid content is 15~21 g/L.

laterite nickel orelimonite typeserpentinite typemixed acid maturationwater leachingpreleachingpressurized leaching

杨均流、徐敬元、肖桂龙

展开 >

巴斯夫(中国)有限公司,上海 200120

北方矿业有限责任公司,北京 100053

埃赫曼(上海)贸易有限公司,上海 200120

红土镍矿 褐铁矿型 蛇纹石型 拌酸熟化 水浸 预浸 加压浸出

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(7)