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废钯催化剂浸出液中钯的硫化沉淀试验研究

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湿法工艺是废钯催化剂的主流回收工艺,作为经典的传统湿法工艺,焙烧-浸出-置换-提纯工艺既有显著优势,也存在不足.试验采用HCl-NaClO3 体系对废钯催化剂进行浸出,研究硫化沉淀的影响因素,揭示PdS的沉淀规律,完善工艺参数,实现技术优化,为产业化应用提供可靠的理论基础.研究表明,硫化沉淀法可以代替产渣量巨大的铁置换法,钯沉淀率可以达到 99.99%,尾液的贵金属含量达到相关排放标准,浸出液中的钯实现高效富集.
Experimental Study on Sulfide Precipitation of Palladium in Leachate of Waste Palladium Catalyst
The wet process is the mainstream recycling process for waste palladium catalysts,as a classic traditional wet process,the roasting-leaching-displacement-purification process has both significant advantages and disadvantages.The experiment uses HCl-NaClO3 system to leach waste palladium catalyst,studies the influencing factors of sulfide precipitation,reveals the precipitation law of PdS,improves process parameters,achieves technical optimization,and provides a reliable theoretical basis for industrial application.Research has shown that the sulfide precipitation method can replace the iron displacement method,which produces a large amount of slag,the palladium precipitation rate can reach 99.99%,and the precious metal content in the tailings meets the relevant emission standards,and the palladium in the leachate can be efficiently enriched.

waste palladium catalystleachatepalladiumenrichmentrecyclingsulfide precipitation

张帆、吴祖璇、王芳、刘昱辰、张金池

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江苏北矿金属循环利用科技有限公司,江苏 徐州 221121

废钯催化剂 浸出液 富集 回收 硫化沉淀

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(7)