首页|气象要素对近地层臭氧污染形成的影响研究

气象要素对近地层臭氧污染形成的影响研究

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近地层臭氧(O3)是对人体健康和植被生长有害的重要污染物,O3 的形成受气象条件(扩散、稀释等物理过程)、化学反应生成/去除速率和源排放强度的共同影响.以山东省临沂市为研究区,根据 2019-2022 年的O3 历史监测数据及气象资料,深入分析温度、相对湿度、风速、降水量和风向等气象要素的不同区间下近地层O3 的变化特征,明确气象要素对O3 前体物挥发性有机物(Volatile Organic Compounds,VOCs)浓度的影响.研究结果表明,O3 浓度与温度呈正相关,与相对湿度、降水和风速呈负相关.平均温度介于 25~30℃,日最大温度大于 35℃,温差大于 8℃时,O3 浓度最容易超标,平均温度、日最大温度和温差均能指示O3 超标现象,但温差与日最大温度的影响比较明显.当温度为25~35℃,相对湿度为 40%~60%时,临沂市O3 浓度易出现高值.温度和相对湿度对VOCs存在相反的影响.当风速小于 2 m/s时,VOCs浓度最高.随着风速的逐渐增加,VOCs浓度逐渐减小.当临沂市盛行偏南风且风速为 6~8 m/s时,要格外注意O3 的污染动向.研究成果有助于理解O3 在大气中的传输扩散、化学反应过程,并可以用来初步判断O3 来源,为城市O3 来源解析提供支撑.
Study on the Impact of Meteorological Elements on the Formation of Near Surface Ozone Pollution
The near surface ozone(O3)is an important pollutant that is harmful to human health and vegetation growth,and the formation of O3 is influenced by meteorological conditions(diffusion,dilution,and other physical processes),chemical reaction generation/removal rates,and source emission intensity.Taking Linyi city,Shandong province as the research area,based on historical monitoring data and meteorological data of O3 from 2019 to 2022,the variation characteristics of near surface O3 is deeply analyzed in different intervals of meteorological elements such as temperature,relative humidity,wind speed,precipitation,and wind direction,and the influence of meteorological elements is clarified on the concentration of Volatile Organic Compounds(VOCs)in O3 precursors.The research results indicate that O3 concentration is positively correlated with temperature and negatively correlated with relative humidity,precipitation,and wind speed.When the average temperature is 25~30℃,the daily maximum temperature is greater than 35℃,and the temperature difference is greater than 8℃,the O3 concentration is most likely to exceed the standard,and the average temperature,daily maximum temperature,and temperature difference can all indicate the phenomenon of O3 exceeding the standard,but the influence of temperature difference and daily maximum temperature is more obvious.When the temperature is 25~35℃and the relative humidity is 40%~60%,the O3 concentration in Linyi city is prone to high values,and temperature and relative humidity have opposite effects on VOCs. When the wind speed is less than 2 m/s,the concentration of VOCs is highest. As the wind speed gradually increases,the concentration of VOCs gradually decreases. When southerly winds prevail in Linyi city with wind speeds of 6~8 m/s,special attention should be paid to the pollution trend of O3. The research results contribute to understanding the transport,diffusion,and chemical reaction processes of O3 in the atmosphere,and can be used to preliminarily determine the source of O3,providing support for the analysis of O3 sources in cities.

meteorological elementsnear surfaceozone pollutionVolatile Organic Compounds(VOCs)

朱帅帅

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山东省环境保护科学研究设计院有限公司,济南 250013

气象要素 近地层 臭氧污染 挥发性有机物(VOCs)

生态环境部细颗粒物与臭氧污染协同防控"一市一策"驻点跟踪研究项目

DQGG2021-25

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(7)