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富碳气化渣表面性质及浮选研究

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气化渣是煤化工行业主要固体废弃物,借助选矿手段可以有效将气化渣中的未燃碳与硅酸盐相分离,增加其工业利用价值.分析了气化渣重选精矿(富碳气化渣)的比表面积、红外光谱仪和X射线光电子能谱,研究了气化渣的可浮性行为.试验结果表明,富碳气化渣比表面积为286.32 m2/g,平均孔径为3.30 nm,其表面含有大量含氧官能团,碳原子与氧原子含量别为52.32%和42.42%,表面亲水性较高.采用月桂酸甲酯和煤油复配捕收剂+十二烷基苯磺酸钠+二步浮选法浮选效果最好,精矿灰分为27.47%,精矿产率为8.23%.
Surface Properties and Flotation Research of Carbon Rich Gasification Slag
Gasification slag is the main solid waste in the coal chemical industry,and with the help of beneficiation means,the unburned carbon and silicate phases in gasification slag can be effectively separated to increase its industrial utilization value.The specific surface area,infrared spectroscopy and X-ray photoelectron spectroscopy of gasification slag reelected concentrate(carbon-rich gasification slag)were analyzed,and the floatable behavior of gasification slag was studied.The test results showed that the specific surface area of the carbon-rich gasification slag was 286.32 m2/g,the average pore size was 3.30 nm,and its surface contained a large number of oxygen-containing functional groups,with the contents of carbon atoms and oxygen atoms of 52.32%and 42.42%,respectively,and the surface hydrophilicity was high.The best flotation effect was achieved by using methyl laurate and kerosene compound collector+sodium dodecylbenzene sulfonate+two-step flotation method,with a concentrate ash content of 27.47%and a concentrate yield of 8.23%.

gasification slagspecific surface areahydrophilicityflotation

孙小乐、睢月婷、南凯、史培阳

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包钢集团矿山研究院(有限责任公司),内蒙古 包头 014000

东北大学多金属共生矿生态化冶金教育部重点实验室,沈阳 110819

气化渣 比表面积 亲水性 浮选

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(8)