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危险废物工业指标热失重性能研究

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危险废物工业指标包括水分、挥发分、固定碳和灰分,其热失重性能对回转窑危险废物处置的配伍和工艺调整具有重要影响.试验研究 3 种模拟物、5 种复配危险废物和 7 种典型危险废物的热失重性能.结果表明,危险废物质量损失可以分为 3 个阶段,水分失重段温度为 200~300℃,挥发分失重段温度为 450~543℃,固定碳失重段温度为 759~774℃.水分干燥和挥发分挥发可能同时发生,失重较快,挥发分挥发和固定碳燃尽不会同时发生,固定碳失重较慢.危险废物水分和挥发分失重占总时间的10%~20%,而固定碳的失重占总时间的 80%~90%.在配伍过程中,要做好工业指标控制.总体来说,水分含量应小于 20%,挥发分含量为 50%~70%,固定碳含量为 5%~10%,灰分含量为 15%~20%.研究结果可指导回转窑危险废物处置过程的配伍,调整焚烧工艺.
Study on the Thermo Gravimetric Performance of Industrial Indicators for Hazardous Waste
The industrial indicators of hazardous waste include moisture,volatile matter,fixed carbon,and ash content,and their thermo gravimetric performance has a significant impact on the compatibility and process adjustment of rotary kiln hazardous waste disposal.The thermal gravimetric properties of three simulated substances,five complex hazardous wastes,and seven typical hazardous wastes are studied in the experiment.The results indicate that the quality loss of hazardous waste can be divided into three stages,the temperature of the water loss stage is 200~300℃,the temperature of the volatile matter loss stage is 450~543℃,and the temperature of the fixed carbon loss stage is 759~774℃.Moisture drying and volatile matter volatilization may occur simultaneously,resulting in rapid weight loss,and volatile matter volatilization and fixed carbon burnout will not occur simultaneously,while fixed carbon weight loss is slower.The weight loss of hazardous waste moisture and volatile matter accounts for 10%~20%of the total time,while the weight loss of fixed carbon accounts for 80%~90%of the total time.During the compatibility process,it is important to ensure proper control of industrial indicators.Overall,the moisture content should be less than 20%,the volatile matter content should be 50%~70%,the fixed carbon content should be 5%~10%,and the ash content should be 15%~20%.The research results can guide the compatibility of hazardous waste disposal processes in rotary kilns and adjust incineration processes.

hazardous wasterotary kilnindustrial indicatorsthermo gravimetric performance

宋西义、崔磊、张少篪、邓智伟

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江苏永之清固废处置有限公司,江苏 苏州 215500

奥特拉斯环保科技(临沂)有限公司,山东 临沂 276000

危险废物 回转窑 工业指标 热失重性能

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(10)