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电化学强化人工湿地对四环素类抗生素的去除研究

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四环素类抗生素因其化学性质稳定难以被传统污水工艺去除,且易在水体中富集,致使耐药性问题的产生.因此,本研究采用生物处理-电化学强化人工湿地组合工艺去除生活污水中的四环素类抗生素.对比了电解、铁碳微电解和电解耦合铁碳微电解强化人工湿地对四环素类抗生素的去除效果.试验结果表明,经过生物处理系统,四环素类抗生素仍有部分残留,生物处理系统对土霉素的去除率最高,去除率为60.29%;经过人工湿地处理,4 种抗生素均得到强化去除,电解耦合铁碳微电解强化人工湿地对四环素、土霉素、多西环素的去除效果最佳.生物处理组合人工湿地系统对土霉素、四环素的最高去除率分别达到71.6%和 71.23%,且能有效去除多西环素和金霉素.电解耦合铁碳微电解强化作用对四环素类抗生素具有良好的去除效果,有较好的应用和推广潜力.
Study on Removal of Tetracycline Antibiotics by Electrochemical Enhanced Constructed Wetland
Tetracycline antibiotics are difficult to remove by traditional sewage processes due to their stable chemical properties,and are prone to accumulation in water bodies,leading to the emergence of drug resistance problems.Therefore,this study adopted a combination process of biological treatment and electrochemical enhanced constructed wetland to remove tetracycline antibiotics from domestic sewage.We compared the removal efficiency of tetracycline antibiotics by electrolysis,iron carbon microelectrolysis,and electrolysis coupled iron carbon microelectrolysis enhanced artificial wetlands.The experimental results showed that after the biological treatment system,there were still some residues of tetracycline antibiotics,and the biological treatment system had the highest removal rate of oxytetracycline,with a removal rate of 60.29%;After treatment with artificial wetlands,all four antibiotics were effectively removed.The electrolytic coupled iron carbon microelectrolysis enhanced artificial wetlands showed the best removal effect on tetracycline,oxytetracycline,and doxycycline.The biological treatment combined with artificial wetland system achieved the highest removal rates of 71.6%and 71.23%for oxytetracycline and tetracycline,respectively,and could effectively remove doxycycline and chlortetracycline.The electrolytic coupling iron carbon microelectrolysis strengthening effect has a good removal effect on tetracycline antibiotics and has good potential for application and promotion.

electrolysisconstructed wetlandtetracycline antibiotics

黑生磊、余凯锋、王亚娥

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兰州交通大学环境与市政工程学院,兰州 730070

上海交通大学环境科学与工程学院,上海 200240

电解 人工湿地 四环素类抗生素

2024

中国资源综合利用
徐州北矿金属循环利用研究所 中国物资再生协会

中国资源综合利用

CHSSCD
影响因子:0.358
ISSN:1008-9500
年,卷(期):2024.42(10)