中国造纸2024,Vol.43Issue(1) :38-50.DOI:10.11980/j.issn.0254-508X.2024.01.005

纤维性能对纸张水蒸气阻隔性能的影响

Effect of Fiber Properties on Water Vapor Barrier Performance of Paper

胡小莉 张雪 张红杰 侯磊磊 程芸 田超
中国造纸2024,Vol.43Issue(1) :38-50.DOI:10.11980/j.issn.0254-508X.2024.01.005

纤维性能对纸张水蒸气阻隔性能的影响

Effect of Fiber Properties on Water Vapor Barrier Performance of Paper

胡小莉 1张雪 2张红杰 1侯磊磊 1程芸 1田超1
扫码查看

作者信息

  • 1. 中国制浆造纸研究院有限公司,北京,100102;制浆造纸国家工程实验室,北京,100102
  • 2. 中国制浆造纸研究院有限公司,北京,100102;华南理工大学制浆造纸工程国家重点实验室,广东广州,510640;广东壮丽彩印股份有限公司,广东汕头,515041;制浆造纸国家工程实验室,北京,100102
  • 折叠

摘要

本研究利用不同种类、不同程度打浆处理及硅烷化改性的纸浆纤维,制备物化性能不同的纸张,调控纸张的三维孔隙结构,从纤维的物理性能和化学疏水改性对纸张结构影响的角度,探讨纤维性能(打浆度、纤维长度及分布、保水值、纤维形貌和亲/疏水性等)对纸张水蒸气阻隔性能的影响.结果表明,纸张的水蒸气阻隔性能受纤维打浆度和亲/疏水性的影响较大.测试条件(23±0.5)℃、相对湿度(50±1)%时,打浆度从13.5 °SR增至90 °SR的未漂化学针叶木浆制备的定量60g/m2纸张的水蒸气透过率从954.5 g/(m2·d)降低至93.77 g/(m2·d);测试条件为(23±0.5)℃、相对湿度(75±1)%时,疏水改性纤维纸张比未改性纤维纸张的水蒸气透过率降低了 11.6%,纸张的水蒸气透过率受疏水改性纤维配抄比例的影响较大.

Abstract

In this study,paper with different physicochemical properties were prepared by using different types of pulp fibers with different degrees of pulping treatment and silane modification to regulate the three-dimensional structure of paper.From the viewpoint of the effects of fiber physical properties and chemical hydrophobic modifications on paper structure,the effects of fiber properties(beating degree,fi-ber length and distribution,water retention value,fiber morphology and hydrophilic/hydrophobic property)on the water vapor barrier per-formance of paper were investigated.The results showed that the water vapor barrier performance of the paper was influenced by the beat-ing degree and hydrophilic/hydrophobic of the fibers.Under the testing conditions of(23±0.5)℃ and(50±1)%RH,the water vapor trans-mission rate of the paper with a basis weight of 60 g/m2 was reduced from 954.5 to 93.77 g/(m2·d),when the beating degree of the un-bleached pine pulp was increased from 13.5 to 90 °SR.The water vapor transmission rate of the paper prepared by hydrophobic modified fiber was reduced by 11.6%compared with that of unmodified fiber when the test conditions were(23±0.5)℃ and(75±1)%RH.The wa-ter vapor transmission rate of paper was influenced by the mixing proportion of hydrophobic modified fiber.

关键词

纤维形态/润湿性能/水蒸气阻隔性能/三维孔隙结构

Key words

fiber morphology/wettability/water vapor barrier performance/three-dimensional pore structure

引用本文复制引用

基金项目

国家自然科学基金(32001276)

国家自然科学基金(32171727)

中轻集团科技创新重点专项(ZQ2022JC-QN01)

出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
参考文献量20
段落导航相关论文