首页|纤维性能对纸张水蒸气阻隔性能的影响

纤维性能对纸张水蒸气阻隔性能的影响

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本研究利用不同种类、不同程度打浆处理及硅烷化改性的纸浆纤维,制备物化性能不同的纸张,调控纸张的三维孔隙结构,从纤维的物理性能和化学疏水改性对纸张结构影响的角度,探讨纤维性能(打浆度、纤维长度及分布、保水值、纤维形貌和亲/疏水性等)对纸张水蒸气阻隔性能的影响.结果表明,纸张的水蒸气阻隔性能受纤维打浆度和亲/疏水性的影响较大.测试条件(23±0.5)℃、相对湿度(50±1)%时,打浆度从13.5 °SR增至90 °SR的未漂化学针叶木浆制备的定量60g/m2纸张的水蒸气透过率从954.5 g/(m2·d)降低至93.77 g/(m2·d);测试条件为(23±0.5)℃、相对湿度(75±1)%时,疏水改性纤维纸张比未改性纤维纸张的水蒸气透过率降低了 11.6%,纸张的水蒸气透过率受疏水改性纤维配抄比例的影响较大.
Effect of Fiber Properties on Water Vapor Barrier Performance of Paper
In this study,paper with different physicochemical properties were prepared by using different types of pulp fibers with different degrees of pulping treatment and silane modification to regulate the three-dimensional structure of paper.From the viewpoint of the effects of fiber physical properties and chemical hydrophobic modifications on paper structure,the effects of fiber properties(beating degree,fi-ber length and distribution,water retention value,fiber morphology and hydrophilic/hydrophobic property)on the water vapor barrier per-formance of paper were investigated.The results showed that the water vapor barrier performance of the paper was influenced by the beat-ing degree and hydrophilic/hydrophobic of the fibers.Under the testing conditions of(23±0.5)℃ and(50±1)%RH,the water vapor trans-mission rate of the paper with a basis weight of 60 g/m2 was reduced from 954.5 to 93.77 g/(m2·d),when the beating degree of the un-bleached pine pulp was increased from 13.5 to 90 °SR.The water vapor transmission rate of the paper prepared by hydrophobic modified fiber was reduced by 11.6%compared with that of unmodified fiber when the test conditions were(23±0.5)℃ and(75±1)%RH.The wa-ter vapor transmission rate of paper was influenced by the mixing proportion of hydrophobic modified fiber.

fiber morphologywettabilitywater vapor barrier performancethree-dimensional pore structure

胡小莉、张雪、张红杰、侯磊磊、程芸、田超

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中国制浆造纸研究院有限公司,北京,100102

制浆造纸国家工程实验室,北京,100102

华南理工大学制浆造纸工程国家重点实验室,广东广州,510640

广东壮丽彩印股份有限公司,广东汕头,515041

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纤维形态 润湿性能 水蒸气阻隔性能 三维孔隙结构

国家自然科学基金国家自然科学基金中轻集团科技创新重点专项

3200127632171727ZQ2022JC-QN01

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(1)
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