中国造纸2024,Vol.43Issue(2) :9-18.DOI:10.11980/j.issn.0254-508X.2024.02.002

电纺木质素基磁性碳纳米纤维的制备及其电磁屏蔽应用

Lignin-based Electrospun Magnetic Carbon Nanofibers and Their Application for Electromagnetic Shielding

周柄旭 段超 田国栋 周琳琳 谢增颖 王强
中国造纸2024,Vol.43Issue(2) :9-18.DOI:10.11980/j.issn.0254-508X.2024.02.002

电纺木质素基磁性碳纳米纤维的制备及其电磁屏蔽应用

Lignin-based Electrospun Magnetic Carbon Nanofibers and Their Application for Electromagnetic Shielding

周柄旭 1段超 2田国栋 1周琳琳 1谢增颖 3王强4
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作者信息

  • 1. 陕西科技大学轻工科学与工程学院,陕西西安,710021
  • 2. 陕西科技大学轻工科学与工程学院,陕西西安,710021;宜宾丝丽雅集团有限公司,四川宜宾,644000;齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,山东济南,250353
  • 3. 宜宾丝丽雅集团有限公司,四川宜宾,644000
  • 4. 齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,山东济南,250353
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摘要

本研究以碱木质素(AL)和聚丙烯腈(PAN)为原料,通过预掺杂FeNi金属盐前驱体,利用静电纺丝和高温碳化工艺,制备出具有优异电磁屏蔽效能的电纺木质素基磁性碳纳米纤维(FeNi@LCNF).结果表明,最佳电纺纤维的AL用量为50%,且当FeNi的负载量为17.3%时,FeNi@LCNF-2呈现良好的导电性和铁磁性;在铁镍元素的催化下,碳化后的电纺纤维表面具有众多"荆棘状"碳纳米管,促进了碳纤维材料的多孔导电网络和异质结构形成,进而赋予FeNi@LCNF-2较高的电导率(8.11S/cm),使其在X波段内具有38.0dB的电磁屏蔽效能.

Abstract

In this study,the alkali lignin(AL)and polyacrylonitrile(PAN)were used as raw materials to prepare lignin-based magnetic car-bon nanofibers(FeNi@LCNF)with great electromagnetic shielding effectiveness(EMI SE),and its preparation process consisted of pre-doping of Fe and Ni precursors,electrospinning,and carbonization processes.The results showed that when the AL dosage was 50%,the electrospun fiber was optimal.When the FeNi loading capacity was 17.3%,the as-prepared FeNi@LCNF-2 exhibited high electrical conduc-tivity and ferromagnetism.In addition,under the catalysis of Fe and Ni elements,numerous"thorn-like"carbon nanotubes in-situ grew on the surfaces of the carbon nanofibers,which further promoted the formation of porous conductive network and heterostructure of the carbon fi-ber material,thus endowed high conductivity(8.11 S/cm)of FeNi@LCNF-2 and 38 dB of EMI SE in the X-band.

关键词

静电纺丝/木质素/碳化/碳纳米纤维/电磁屏蔽

Key words

electrospinning/lignin/carbonization/carbon nanofiber/electromagnetic shielding

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基金项目

国家自然科学基金面上项目(22178206)

宜宾市科技局"揭榜挂帅"项目(2022JB011)

生物基材料与绿色造纸国家重点实验室开放基金(GZKF202025)

出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
参考文献量24
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