首页|电纺木质素基磁性碳纳米纤维的制备及其电磁屏蔽应用

电纺木质素基磁性碳纳米纤维的制备及其电磁屏蔽应用

扫码查看
本研究以碱木质素(AL)和聚丙烯腈(PAN)为原料,通过预掺杂FeNi金属盐前驱体,利用静电纺丝和高温碳化工艺,制备出具有优异电磁屏蔽效能的电纺木质素基磁性碳纳米纤维(FeNi@LCNF).结果表明,最佳电纺纤维的AL用量为50%,且当FeNi的负载量为17.3%时,FeNi@LCNF-2呈现良好的导电性和铁磁性;在铁镍元素的催化下,碳化后的电纺纤维表面具有众多"荆棘状"碳纳米管,促进了碳纤维材料的多孔导电网络和异质结构形成,进而赋予FeNi@LCNF-2较高的电导率(8.11S/cm),使其在X波段内具有38.0dB的电磁屏蔽效能.
Lignin-based Electrospun Magnetic Carbon Nanofibers and Their Application for Electromagnetic Shielding
In this study,the alkali lignin(AL)and polyacrylonitrile(PAN)were used as raw materials to prepare lignin-based magnetic car-bon nanofibers(FeNi@LCNF)with great electromagnetic shielding effectiveness(EMI SE),and its preparation process consisted of pre-doping of Fe and Ni precursors,electrospinning,and carbonization processes.The results showed that when the AL dosage was 50%,the electrospun fiber was optimal.When the FeNi loading capacity was 17.3%,the as-prepared FeNi@LCNF-2 exhibited high electrical conduc-tivity and ferromagnetism.In addition,under the catalysis of Fe and Ni elements,numerous"thorn-like"carbon nanotubes in-situ grew on the surfaces of the carbon nanofibers,which further promoted the formation of porous conductive network and heterostructure of the carbon fi-ber material,thus endowed high conductivity(8.11 S/cm)of FeNi@LCNF-2 and 38 dB of EMI SE in the X-band.

electrospinninglignincarbonizationcarbon nanofiberelectromagnetic shielding

周柄旭、段超、田国栋、周琳琳、谢增颖、王强

展开 >

陕西科技大学轻工科学与工程学院,陕西西安,710021

宜宾丝丽雅集团有限公司,四川宜宾,644000

齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,山东济南,250353

静电纺丝 木质素 碳化 碳纳米纤维 电磁屏蔽

国家自然科学基金面上项目宜宾市科技局"揭榜挂帅"项目生物基材料与绿色造纸国家重点实验室开放基金

221782062022JB011GZKF202025

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(2)
  • 24