首页|再生木质素粒子增强纤维素透明膜的性能研究

再生木质素粒子增强纤维素透明膜的性能研究

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本研究以硫酸盐制浆黑液为原料,通过钙离子螯合的方式提取粗制木质素,利用乙醇-水反溶剂法溶解再生以获得高纯度的木质素粒子.呈现细小均匀的颗粒形态并稳定悬浮在水中的再生木质素粒子能够与纤维素形成强氢键结合,并形成致密均匀的复合透明薄膜.木质素-纤维素复合膜(木质素添加量10%)的抗拉强度达105.77 MPa,相比于纯纤维素膜提高了27.6%;伸长率增幅67.6%.在光学方面,木质素-纤维素膜(木质素添加量5%)的可见光透过率可达87.9%.
Study on the Properties of Cellulose Transparent Films Reinforced with Regenerated Lignin Particles
Crude lignin was extracted from sulfate pulping black liquor by chelation with calcium ions.Subsequently,the crude lignin under-went dissolution and regeneration by employing an ethanol-water anti-solvent method,resulting in the production of pure lignin particles.The resulting regenerated lignin particles demonstrated a fine and uniform granular morphology while remaining stably suspended in water.Lignin particles could form robust hydrogen bonds with cellulose,leading to the formation of dense and uniform composite transparent films.The tensile strength of the lignin-cellulose film(the dosage of lignin was 10%)reached 105.77 MPa,an increase of 27.6%compared with the pure cellulose film,the elongation increased by 67.6%.In terms of optics,the visible light transmittance of the lignin-cellulose film(the dosage of lignin was 5%)reached 87.9%.

black liquorregenerated lignin particlescalcium acetatelignin-cellulose film

傅成龙、林亚玲、刘一山、黄六莲

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福建农林大学材料工程学院,福建福州,350108

新布伦瑞克大学Limerick制浆造纸中心,新布伦瑞克弗雷德里克顿,E3B5A3,加拿大

四川工商职业技术学院,四川都江堰,611830

黑液 再生木质素粒子 乙酸钙 木质素-纤维素膜

高校产学合作项目国家留学基金委项目四川省科技厅项目四川省科技厅项目

2021H60242022083500632021YFH01052023JDGD0032

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(2)
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