中国造纸2024,Vol.43Issue(3) :1-8,64.DOI:10.11980/j.issn.0254-508X.2024.03.001

3D打印碳纳米管/纳米纤维素复合电极制备及性能

3D Printed Preparation and Properties of Carbon Nanotube/Nanocellulose Composite Electrode

张素风 王小一 刘亚丽 贺鑫宁
中国造纸2024,Vol.43Issue(3) :1-8,64.DOI:10.11980/j.issn.0254-508X.2024.03.001

3D打印碳纳米管/纳米纤维素复合电极制备及性能

3D Printed Preparation and Properties of Carbon Nanotube/Nanocellulose Composite Electrode

张素风 1王小一 1刘亚丽 1贺鑫宁1
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作者信息

  • 1. 陕西科技大学轻工科学与工程学院,陕西西安,710021
  • 折叠

摘要

本研究探索了基于光固化的3D打印技术制造导电聚合物树脂材料.以可光固化树脂和多壁碳纳米管(MWCNT)混合物为基底,通过添加纳米纤维素(CNF)来改善MWCNT的分散性,使混合树脂达到最佳的导电性能和印刷质量.此外,结合了光固化、热解和化学活化等反应过程,形成可设计的分级孔结构的碳电极,该电极具有从毫米级到微米级再到纳米级分布的孔隙结构,组装对称超级电容器可提供高能量密度0.91 mWh/cm2.

Abstract

This study explored a visible light-based 3D printing technology for the fabrication of conductive polymer resin materials.A mix-ture of light-curable resin and multi-walled carbon nanotube(MWCNT)was used as the substrate,and the dispersibility of MWCNT was im-proved by adding nanocelluloses(CNF)to achieve the best electrical conductivity and printing quality of the hybrid resin.In addition,light curing,pyrolysis,and chemical activation were combined to form carbon electrodes with designable hierarchical pore structures.The elec-trodes had pore structures with a distribution from millimeter to micron to nanometer scale,and assembled symmetric supercapacitors were provided a high energy density of 0.91 mWh/cm2.

关键词

光固化/3D打印/纳米纤维素/碳纳米管/电极材料

Key words

light-curable/3D printing/nanocellulose/carbon nanotube/electrode material

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基金项目

国家自然科学基金(22078187)

生物质化学与材料国际联合研究中心(2018GHJD-19)

陕西省重点产业创新链项目(2020ZDLGY11-03)

出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
参考文献量29
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