首页|Fe基类Fenton催化剂非均相处理造纸废水

Fe基类Fenton催化剂非均相处理造纸废水

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针对传统均相Fenton法深度处理造纸废水中铁泥量大、成本较高等问题,将Fe2O3、Al203、Si02、石墨粉采用高温烧结的方式,制备Fe基类Fenton催化剂,并用于非均相Fenton处理造纸废水,可达到节省FeSO4用量的效果.结果表明,经高温烧结制备的Fe基类Fenton催化剂具有丰富的孔隙结构,在pH值为3、催化剂投加量15 g/L、CODCr和H202质量比1∶0.75、反应时间90 min的条件下,造纸废水CODCr去除率为74.8%,且经过10次循环实验仍达70%以上,BOD5去除率可达67%以上.
Fe-derived Fenton-like Catalyst for Non-homogeneous Treatment of Papermaking Wastewater
To solve the problems of large amount of iron sludge and high cost in the traditional homogeneous Fenton method for the deep treat-ment of papermaking wastewater,Fe-derived Fenton catalysts were prepared by high temperature sintering of Fe2O3,Al2O3,SiO2,and graphite powder,which was used in the non-homogeneous Fenton treatment of papermaking wastewater to achieve the effect of saving the dosage of Fe-SO4.The results showed that the Fe-derived Fenton-like catalyst prepared by high-temperature sintering had a rich pore structure.Under the conditions that pH value of 3,catalyst dosage of 15 g/L,mass ratio of CODCr and H2O2 of 1∶0.75,and reaction time of 90 min,the removal rate of CODCr was up to 74.8%and more than 70%even after 10 cycles of experiments.The removal rate of BOD5 could be more than 67%.

high-temperature sinteringFenton-like catalystpapermaking wastewaternon-homogeneous Fenton

宗晓宁、罗清、张安龙、井天昊、刘育星

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陕西科技大学轻工科学与工程学院,轻化工程国家级实验教学示范中心,陕西西安,710021

陕西科技大学环境科学与工程学院,陕西西安,710021

高温烧结 类Fenton催化剂 造纸废水 非均相Fenton

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(3)
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