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酸/碱性低共熔溶剂预处理对轻木物化性质及酶水解影响

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采用酸/碱性低共熔溶剂(DES)在110℃和5 h下预处理轻木原料,分析了预处理前后轻木的化学组成、表面形貌、结构变化和酶水解性能.结果表明,3种酸/碱性DES预处理均可有效解构轻木原料.酸性DES可去除几乎所有的半纤维素和部分木质素,且酸性较强的氯化铝六水合物/丙三醇体系处理导致部分纤维素降解.碱性氯化胆碱/乙醇胺体系预处理后木质素大量去除,残留物中保留大量碳水化合物.预处理可显著增效纤维素酶水解,葡萄糖得率由原料的16.5%提升至52.6%~60.7%.DES经循环使用3次后纤维素酶解效率仍可达原料的2.5倍以上.
Effects of Pretreatment with Acidic/Alkaline Deep Eutectic Solvents on Physical and Chemical Properties and Cellulose Enzymatic Hydrolysis of Balsa Wood
Balsa wood was subjected to acidic/alkaline deep eutectic solvent(DES)pretreatment at 110℃for 5 h,and the chemical compo-sition,surface morphology,structural variation,and enzymatic hydrolysis performance of the balsa wood before and after pretreatment were analyzed.The results showed that all three types of acidic/alkaline DES pretreatments effectively deconstructed the balsa wood raw material.The acidic DES removed nearly all hemicelluloses and a portion of lignin,with the stronger acidic treatment using acidic aluminum chloride hexahydrate/propanetriol system resulting in partial cellulose degradation.The alkaline choline chloride/ethanolamine system pretreatment led to substantial removal of lignin while preserving a significant amount of carbohydrates in the residue.The pretreatment significantly en-hanced cellulase hydrolysis,increasing the glucose yield from 16.5%in the raw material to 52.6%~60.7%.Even after being recycled three times,the cellulose hydrolysis rate of DES remained more than 2.5 times higher than that of the raw material.

balsa wooddeep eutectic solventpretreatmentenzymatic hydrolysisrecycling

唐义泉、芮安娜、杨积有、商赛男、司传领、边静

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北京林业大学林木生物质化学北京市重点实验室,北京,100083

天津科技大学天津市制浆造纸重点实验室,天津,300457

轻木 低共熔溶剂 预处理 酶解 循环使用

国家自然科学基金

32271804

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(6)