首页|预水解硫酸盐竹浆的漂白工艺研究

预水解硫酸盐竹浆的漂白工艺研究

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本研究以预水解硫酸盐未漂竹浆为原料,采用"氧脱木质素(O)-氯漂(D0)-氧和过氧化氢强化碱抽提(Eop)-氯漂(D1)"的漂白工艺制备可用作溶解浆的竹浆.通过优化各工段的处理条件(氧漂白段:氢氧化钠用量2.0%、氧压0.5 MPa、反应时间60 min、反应温度95 ℃;D0漂白段:二氧化氯用量3.5%、反应时间80min、反应温度70℃、初始pH值4.0;Eop漂白段:过氧化氢用量1.4%、氧压0.2 MPa、反应时间90 min、反应温度90 ℃、初始pH值11.5;D1漂白段:二氧化氯用量1.5%、反应时间150min、反应温度70 ℃、初始pH值4.0),最终制备白度82.7%、黏度440.0mL/g、灰分含量0.24%、α-纤维素含量90.92%的竹浆.
Study on Bleaching Process of Pre-hydrolyzed Bamboo Sulfate Pulp
Using pre-hydrolyzed sulfate unbleached bamboo pulp as raw material,the dissolved bamboo pulp was prepared by the bleaching process of"oxygen delignification(O)-first stage chlorine bleaching(D0)-oxygen and hydrogen peroxide enhanced alkali extraction(Eop)-second stage chlorine bleaching(D1)".The treatment conditions of each section were optimized(O bleaching stage:sodium hydroxide dosage of 2.0%,oxygen pressure of 0.5 MPa,reaction time of 60 min,reaction temperature of 95 ℃;D0 bleaching stage:chlorine dioxide dosage of 3.5%,reaction time of 80 min,reaction temperature of 70 ℃,the initial pH value of 4.0;Eop bleaching stage:hydrogen peroxide dosage of 1.4%,oxygen pressure of 0.2 MPa,reaction time of 90 min,reaction temperature of 90 ℃,initial pH value of 11.5;D,bleaching stage:chlorine dioxide dosage of 1.5%,the reaction time of 150 min,the reaction temperature of 70 ℃,the initial pH value of 4.0),and the final prepared bamboo pulp whiteness reached 82.7%,with viscosity of 440 mL/g,ash content of 0.24%,α-cellulose content of 90.92%.

bamboo pulpoxygen delignificationClO2 bleachingEop bleaching

牛胜玥、罗西尧、林凯睿、杨嘉玮、高亚锋、胡会超、李建国、陈礼辉

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福建农林大学材料工程学院,植物纤维功能材料国家林和草原局重点实验室,福建福州,350108

竹浆 氧脱木质素 ClO2漂白 Eop漂白

国家重点研发计划福建省引导性项目

2023YFD22019032023H0008

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(7)
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