中国造纸2024,Vol.43Issue(8) :1-11.DOI:10.11980/j.issn.0254-508X.2024.08.001

MXene/CNF复合气凝胶的制备及其湿敏性能研究

Preparation and Humidity Sensing Properties of MXene/CNF Composite Aerogels

沈湘凌 陈广杰 郭大亮 李静 童欣
中国造纸2024,Vol.43Issue(8) :1-11.DOI:10.11980/j.issn.0254-508X.2024.08.001

MXene/CNF复合气凝胶的制备及其湿敏性能研究

Preparation and Humidity Sensing Properties of MXene/CNF Composite Aerogels

沈湘凌 1陈广杰 1郭大亮 1李静 1童欣1
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作者信息

  • 1. 浙江科技大学环境与资源学院,浙江杭州,310023
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摘要

本研究将新型二维过渡金属碳氮材料(MXene)与纤维素纳米纤维(CNF)复合,通过液氮定向和非定向预冷冻方法,冷冻干燥后制备4种不同MXene/CNF复合气凝胶,探究加入不同类型CNF、MXene和采用不同液氮预冷冻方法对复合气凝胶形貌结构的影响.结果表明,定向单层MXene/TOCNF复合气凝胶形貌最为优异;对其制备的湿度传感器在相对湿度11%~97%的条件下进行了湿敏测试,发现在MXene质量分数10%、相对湿度97%的条件下,传感器响应值增大了 3倍,说明传感器对于高湿度更为敏感,且该传感器在14天内基本稳定.

Abstract

In this study,the novel two-dimensional transition metal carbon and nitrogen material(MXene)was composited with cellulose nanofibers(CNF),and four different kinds of CNF composite aerogel sensors were prepared after freeze-drying by the liquid nitrogen direc-tional and non-directional pre-freezing methods.The impacts of various types of CNF and MXene,with different liquid nitrogen pre-freezing methods on the morphology and structure of the MXene/CNF composite aerogels were investigated.The results showed that the oriented monolayer MXene/TOCNF composite aerogel had the most excellent morphology.Additionally,the humidity sensitivity test was conducted at relative humidity levels ranging from 11%~97%.The results revealed a three times of increase in response value at relative humidity of 97%with MXene dosage of 10%,indicating superior sensitive of the sensor to high humidity.Furthermore,the sensors demonstrated overall stablility within 14 days.

关键词

CNF/MXene/液氮定向冷冻/气凝胶/湿度传感器

Key words

CNF/MXene/liquid nitrogen directional freezing/aerogel/humidity sensor

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出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
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