首页|合成碳酸钙分散稳定性调控及其对纸质文献脱酸效果研究

合成碳酸钙分散稳定性调控及其对纸质文献脱酸效果研究

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本研究提出了以甲基纤维素为分散助剂,对合成碳酸钙分散体系的粒径和分散稳定性进行调控的研究策略;并将合成碳酸钙分散体系应用于酸化纸质文献脱酸处理,并进行耐老化性能评估.研究发现,黏度为1 500mPa·s的甲基纤维素与氢氧化钙以质量比1∶4在二氧化碳氛围中合成的碳酸钙分散体系具有最佳分散稳定性,碳酸钙的平均粒径为108 nm,静置5天仍保持稳定分散.碳酸钙分散体系处理后的旧书纸张的冷抽提pH值从4.7提升到7.7,碱储量为1.95%碳酸钙当量;经过湿热加速老化14天后,脱酸旧书纸张的冷抽提pH值仍保持7.5,碱储量为1.70%碳酸钙当量;脱酸处理后的旧书纸张机械性能明显高于未处理组,色差<1,对字迹油墨无影响,表明该体系对纸质文献具有优异的脱酸性能,并可赋予其耐老化性能.
Research on the Regulation of Dispersion Stability of Synthetic Calcium Carbonate and Its Effect on Deacidification of Paper-based Documents
In this study,the particle size and dispersion stability of synthesized calcium carbonate dispersion system were regulated by meth-ylcellulose as dispersion agent.Then the calcium carbonate dispersion system was applied to the deacidification of acidified paper literature,and the aging resistance was evaluated.The results showed that the calcium carbonate dispersion system synthesized in a carbon dioxide at-mosphere using methylcellulose with viscosity of 1 500 mPa·s and calcium hydroxide at mass ratio of 1∶4 achieved optimal dispersion stabili-ty.The average particle size of the calcium carbonate was 108 nm,and it remained stably dispersed even after standing for 5 days.The pH value of the old-book paper treated with calcium carbonate dispersion system increased from 4.7 to 7.7,the alkali reserve was 1.95%calci-um carbonate equivalent.After accelerated aging for 14 days,the deacidified old-book paper still maintained pH value was 7.5 and the alka-li reserve was 1.70%calcium carbonate equivalent.The mechanical properties of the deacidified old-book paper were significantly higher than those of the untreated group,and the chromatic aberration was less than 1 which had no effect on the handwriting ink,indicating that the system had excellent deacidification and aging resistance to paper-based documents.

paper-based document protectiondeacidificationsynthesis calcium carbonatemethylcellulose

赵赫、何贝、曹显、刘传富、樊慧明、汤栋霖、赵丽红、任俊莉

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华南理工大学轻工科学与工程学院,制浆造纸工程国家重点实验室,广州市岭南文献保护研究中心,广东广州,510640

陕西师范大学材料科学与工程学院,历史文化遗产保护教育部工程研究中心,陕西西安,710119

华南理工大学材料科学与工程学院,广东广州,510640

纸质文献保护 脱酸 合成碳酸钙 甲基纤维素

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(8)