中国造纸2024,Vol.43Issue(11) :98-107.DOI:10.11980/j.issn.0254-508X.2024.11.011

PVA/阳离子淀粉双物理交联植物纤维基泡沫缓冲材料的制备及性能研究

Preparation and Process Optimization of PVA/Cationic Starch Double Cross-linking Plant Fiber-based Foaming Cushioning Materials

苏颖 奎明红 魏渊 贺莹莹 陈港
中国造纸2024,Vol.43Issue(11) :98-107.DOI:10.11980/j.issn.0254-508X.2024.11.011

PVA/阳离子淀粉双物理交联植物纤维基泡沫缓冲材料的制备及性能研究

Preparation and Process Optimization of PVA/Cationic Starch Double Cross-linking Plant Fiber-based Foaming Cushioning Materials

苏颖 1奎明红 2魏渊 1贺莹莹 1陈港1
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作者信息

  • 1. 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640
  • 2. 广东冠豪高新技术股份有限公司,广东湛江,524072
  • 折叠

摘要

本研究利用泡沫成形工艺,结合聚乙烯醇(PVA)和阳离子淀粉(CS)与植物纤维的双物理交联协同作用,构建具有3D骨架网络结构的植物纤维基泡沫缓冲材料.探究了浆浓对泡孔结构及静态压缩性能的影响,采用正交实验和极差分析优化了工艺条件,并表征了植物纤维基泡沫缓冲材料的可回收性.结果表明,当浆浓1.5%,十二烷基硫酸钠(SDS)质量分数3.8%,CS质量分数15%,PVA质量分数12%,转速2500 r/min时,可获得兼具均匀多孔结构、低密度(0.0363 g/cm3)、良好的力学和缓冲性能(弹性模量285.8 kPa,最小缓冲系数4.4),以及可回收(回收率86%)的植物纤维基泡沫缓冲材料(PFF-CM).

Abstract

In this study,a simple approach for manufacturing plant fiber-based cushioning foams featuring 3D (three dimensional) back-bone network was developed,combined the synergistic effect of double physical cross-linking of polyvinyl alcohol (PVA) and cationic starch (CS) with plant fibers,through foam forming process. The effect of the pulp consistency on the cell structure and static compressive perfor-mance of plant fiber-based foam was investigated,the process conditions were optimized by designing the orthogonal experiments and range analysis,and the recyclability of plant fiber-based cushioning foam materials was characterized. The results showed that when the pulp con-sistency was 1.5%,the obtained recyclable (weight recovery efficiency was 86%) plant fiber foam cushioning materials (PFF-CM) under the conditions of SDS with mass ratio of 3.8%,CS with mass ratio of 15%,PVA with mass ratio of 12%,speed of 2500 r/min,showing uni-form porous structure,low density (0.0363 g/cm3),favorable mechanical and cushioning properties (the elastic modulus was 285.8 kPa and the minimum cushioning coefficient was 4.4).

关键词

植物纤维/双交联作用/泡沫成形/缓冲性能/回收性

Key words

plant fibers/double cross-linking/foam forming process/cushioning performance/recyclability

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出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
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