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胍盐改性纳米纤维素制备高强度阻隔包装纸

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利用高碘酸钠氧化纳米纤维素,引入双醛基团,并接枝胍盐制得改性纳米纤维素.以胍盐接枝纳米纤维素为涂料,进行表面涂布,并结合玉米醇溶蛋白,制备内层涂布胍盐接枝纳米纤维素、外层涂布玉米醇溶蛋白的双层涂布纸.结果表明,胍盐成功接枝到双醛纳米纤维素表面,并使纳米纤维素获得了良好的抗菌性能.双层涂布法有效提高了纸张的防油防水能力、抗张强度和耐破度,防油等级达到9级,Cobb60值降低到46.1 g/m2,抗张强度和耐破度分别达到6.30 kN/m和267 kPa,所制包装纸具有良好的油水阻隔效果和机械强度.
Preparation of High-strength Barrier Packaging Paper from Guanidine Salt-modified Nanocellulose
Nanocellulose was oxidated by sodium periodate to introduce dialdehyde groups,followed by grafting the guanidium salt to obtain the modified nanocellulose. Then the guanidinium-grafted nanocellulose was utilized as coating material for surface coating and combined with zein,to produce the double layer coated paper with guanidinium-grafted nanocellulose as the inner layer and zein as the outer layer. The results showed that the guanidium salt was successfully grafted onto the surface of dialdehyde nanocellulose,as well as giving antibacte-rial properties to nanocellulose. The double layer coating method effectively improved the oil and water resistance,tensile strength,and burst strength of paper. The oil resistance grade reached 9,the Cobb60 value decreased to 46.1 g/m2. The tensile strength and burst strength reached 6.30 kN/m and 267 kPa,respectively,and the prepared packaging paper exhibited excellent oil-water barrier properties and me-chanical strength.

dialdehyde oxidationguanidium saltantimicrobial nanocellulosecoating

吴俊怡、蒋晔、杨刚、苑田忠、毛晰丙、谢齐航、沙力争、赵会芳、孙倩玉

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浙江科技大学环境与资源学院,浙江杭州,310023

华邦古楼新材料有限公司,浙江衢州,324400

双醛氧化 胍盐接枝 抗菌纳米纤维素 涂布

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(11)