中国造纸2024,Vol.43Issue(11) :133-140,172.DOI:10.11980/j.issn.0254-508X.2024.11.015

PPTA复合纤维素纤维纸的制备及性能研究

Preparation and Properties of PPTA Composite Cellulose Fiber Paper

董彦惠 王元霞 赵敏 佟健闻 庹新林
中国造纸2024,Vol.43Issue(11) :133-140,172.DOI:10.11980/j.issn.0254-508X.2024.11.015

PPTA复合纤维素纤维纸的制备及性能研究

Preparation and Properties of PPTA Composite Cellulose Fiber Paper

董彦惠 1王元霞 1赵敏 2佟健闻 1庹新林2
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作者信息

  • 1. 沈阳化工大学材料科学与工程学院,辽宁沈阳,110142
  • 2. 清华大学化学工程系,先进材料教育部重点实验室,北京,100084
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摘要

本研究探讨了PPTA与纤维素纤维纸复合的工艺技术,将中等分子质量的聚对苯二甲酰对苯二胺(PPTA)在DMPU/LiCl中溶解并配制成稳定的溶液,采用刮涂法将其定速刮涂至普通的纤维素纤维纸表面,经凝固浴处理,使PPTA在纤维素纤维纸表面形成凝胶涂层,经干燥得到PPTA涂布纤维素纤维纸.PPTA表面涂层的引入改善了纤维素纤维纸表面的致密性和连续性,且其可以与纤维素纤维纸形成牢固的相互作用.在PPTA质量分数约5.7%的条件下,复合纸的拉伸强度从纤维素纤维纸的25.6 MPa提高至79.7 MPa,增长了211%;湿抗张强度从0.134 kN/m提高至0.731 kN/m,增长了446%;撕裂度从316.3 mN提高至662.3 mN,增长了109%,而且复合纸的阻燃性有显著增长,离火3 s内可自行熄灭,复合纸的电击穿强度达20.9 kV/mm,比纤维素纤维纸提高了90%.

Abstract

This paper presented an investigation into the process technology of poly(p-phenylene terephth amide)(PPTA)composite with cellulose fiber paper. The medium molecular weight PPTA was dissolved in DMPU/LiCl and formulated into a stable solution,which was then scraped onto the surface of ordinary cellulose fiber paper by the scraping method at a constant speed. The resulting gel coating was treated with a solidifying bath and subsequently dried to obtain PPTA-coated cellulose fiber paper. The introduction of PPTA surface coating resulted in an improvement in the denseness and continuity of the cellulose fiber paper surface,thereby facilitating a strong interaction with the cellulose fiber paper. The tensile strength of the composite paper increased significantly when the PPTA content was approximately 5.7%. The tensile strength of the cellulose fiber paper was 25.6 MPa,while that of the composite paper was 79.7 MPa,with a 211% increase. Similarly,the wet tensile strength increased from 0.134 kN/m to 0.731 kN/m,with a 446% increase. Additionally,the tear degree increased from 316.3 mN to 662.3 mN,with a 109% increase. Furthermore,the flame retardancy of the composite paper had increased significantly. It could self-extinguish within 3 when exposed to fire. Addi-tionally,the electric breakdown strength of the composite paper was 20.9 kV/mm,which was an 90% increase compared to the original cellulose fiber paper.

关键词

PPTA/纤维素纤维纸/涂布/复合

Key words

PPTA/cellulose fiber paper/coating/composite

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出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
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