首页|负载β-FeOOH/Fe3O4的纤维素/壳聚糖复合气凝胶的制备及其对甲基橙降解性能研究

负载β-FeOOH/Fe3O4的纤维素/壳聚糖复合气凝胶的制备及其对甲基橙降解性能研究

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本研究以纤维素/壳聚糖气凝胶(CCG)为基底,负载可见光催化剂β-FeOOH/Fe3O4,制备β-FeOOH/Fe3O4@CCG复合气凝胶,构筑光Fenton体系提高催化效能.系统研究了不同β-FeOOH/Fe3O4质量比以及不同负载量复合气凝胶对甲基橙(MO)的降解效果,并阐述了光Fenton降解机理.结果表明,在光Fenton降解中,随着β-FeOOH/Fe3O4负载量的增加,MO降解率提高.当β-FeOOH/Fe3O4的质量比为2:1时,复合气凝胶降解能力最高,MO降解率达到89.1%.自由基捕获结果表明,光诱导降解MO的主要活性物质为羟基自由基.
Preparation of Cellulose/Chitosan Composite Aerogels Loaded with β-FeOOH/Fe3O4 and Degradation Performance of Methyl Orange
The study mainly developed the preparation of cellulose/chitosan composite aerogels loaded with visible light catalyst β-FeOOH/Fe3O4,which was subsequently used as a phototropic Fenton-like system to improve the catalytic efficiency.The degradation effect of com-posite aerogels on methyl orange(MO)with different β-FeOOH/Fe3O4 mass ratios and different loadings was systematically investigated,and the phototropic Fenton-like degradation mechanism was elaborated.The results showed that in phototropic Fenton-like degradation,the deg-radation rate of MO increased with the increase of loadings.When the mass ratio of β-FeOOH/Fe3O4 was 2:1,the degradation ability at-tained the optimum state,with a degradation rate of 89.1%.The results of free radical trapping experiments showed that the main active sub-tances for photo-induced degradation of methyl orange could be attributed to hydroxyl radicals.

cellulosepolymorphic ironcomposite aerogelphotocatalysis

杨晓雨、杨祥建、李飞云、陈天影、邹小峰、唐艳军

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浙江理工大学纺织科学与工程学院制浆造纸研究所,浙江 杭州,310018

浙江华丰纸业科技有限公司,浙江安吉,313309

纤维素 多态铁 复合气凝胶 光催化

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(12)