中国造纸2024,Vol.43Issue(12) :52-61.DOI:10.11980/j.issn.0254-508X.2024.12.007

阳离子淀粉/纳米纤维素复合体系施胶对纸张性能的影响研究

Study on the Effects of Cationic Starch/Nanocellulose Composite System Sizing on the Properties of Paper

奎明红 文辉 马洪生 王斌
中国造纸2024,Vol.43Issue(12) :52-61.DOI:10.11980/j.issn.0254-508X.2024.12.007

阳离子淀粉/纳米纤维素复合体系施胶对纸张性能的影响研究

Study on the Effects of Cationic Starch/Nanocellulose Composite System Sizing on the Properties of Paper

奎明红 1文辉 1马洪生 2王斌3
扫码查看

作者信息

  • 1. 广东冠豪高新技术股份有限公司,广东湛江,524072;广东冠豪新材料研发有限公司,广东 广州,511400
  • 2. 广东冠豪新材料研发有限公司,广东 广州,511400;珠海红塔仁恒包装股份有限公司,广东珠海,519000
  • 3. 华南理工大学轻工科学与工程学院,广东 广州,510640
  • 折叠

摘要

构建阳离子淀粉(CS)和纳米纤维素(NC)的CS/NC复合体系,探索其在食品软包材料中的应用价值.本研究选取打浆度24 °SR针叶木浆和打浆度36°SR阔叶木浆作为基纸原料,系统研究了浆内/表面施胶CS/NC复合体系对纸张性能的影响.将CS/NC复合体系用于基纸的浆内施胶,当CS添加量为1.0%(相对于绝干浆,以下同)、纤维素纳米纤丝(J-CNF)添加量0.6%时,纸张的抗张指数和撕裂指数分别达68.6N·m/g和7.79mN·m2/g,相较于基纸分别提高14.1%和18.8%.将CS/NC复合体系用于基纸的表面施胶,胶料固含量为6.5%(J-CNC∶CS=1∶9,质量比)时,施胶纸张透气度下降值达99.4%;单面施胶量为6g/m2时,施胶纸张防油等级可达12级.

Abstract

Cationic starch(CS)and nanocellulose(NC)were used to construct an CS/NC composite system to explore its application value in food soft packaging materials.In this study,softwood pulp and hardwood pulp with beating degrees of 24 and 36 °SR,respectively,were selected as base paper raw materials.A systematic study was conducted on the effects of intra-slurry/surface sizing the CS/NC composite sys-tem on the properties of paper.When the CS/NC composite system was applied in intra-slurry sizing,CS was added at a mass fraction of 1.0%(relative to the oven dry fiber weight,hereafter)with cellulose nanofibers(J-CNF)of 0.6%,the tensile index and tearing index of the handmade sheet reached 68.6 N·m/g and 7.79 mN·m2/g,respectively,representing increases of 14.1%and 18.8%compared to the base paper.When the CS/NC composite system was applied in surface sizing,the air permeability of sized paper decreased by 99.4%at ce-ment solid content 6.5%,with a mass ratio cellulose nanocrystal(J-CNC)to CS of 1∶9.Additionally,when the amount of single-sided siz-ing was 6 g/m2,the oil-proof grade of sized paper achieved grade 12.

关键词

纳米纤维素/阳离子淀粉/食品包装纸/机械性能/阻隔性能

Key words

nanocellulose/cationic starch/food packaging paper/mechanical properties/barrier properties

引用本文复制引用

出版年

2024
中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
段落导航相关论文