首页|烟碱负载MOF@BC复合材料的制备及在加热卷烟薄片中的应用

烟碱负载MOF@BC复合材料的制备及在加热卷烟薄片中的应用

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本研究以β-环糊精(β-CD)和NaOH为原料制备新型金属有机框架(metal-organic framework,MOF)材料,并利用该材料原位修饰细菌纤维素(bacterial cellulose,BC)获得β-CD-MOF@BC复合材料.运用扫描电子显微镜、X射线衍射、热重、热裂解和热脱附等方法,从微观结构、烟碱释放性能、热裂解香味产物等方面对复合材料进行了系统分析.结果表明,本研究制备的负载烟碱的新型β-CD-MOF材料含有丰富的孔径,BC的纤维网格中包埋嵌入了MOF材料,表明MOF材料成功地修饰了BC而形成了一种复合材料;β-CD-MOF@BC复合材料的最大质量损失阶段温度相对空白BC材料延迟了44 ℃,载烟碱释放量增加5.8个百分点,时间延迟1.055 min,对烟碱的负载能力比空白BC材料强,并有一定的缓释性.β-CD-MOF@BC复合材料热脱附释放的香味成分达20种,有利于增加吸食感官品质.
Nicotine Loading MOF@BC Preparation of Composite Materials and Their Application in Heating Cigarette Flakes
In this paper,a new metal-organic framework(MOF)material was prepared with β-cyclodextrin(β-CD)and NaOH as raw materi-als,and the β-CD-MOF@BC composite was obtained by in-situ modification of bacterial cellulose(BC)with the MOF material.A systemat-ic analysis was conducted on the composite materials from the aspects of microstructure,nicotine release performance,and thermal decom-position aroma products using scanning electron microscopy,X-ray diffraction,thermogravimetric experiments,thermal decomposition,and thermal desorption.The results showed that nicotine-loaded MOF materials with abundant pore sizes could be prepared by the new method proposed in this study.Theβ-CD-MOF materials were embedded in the BC fiber mesh,indicating that the MOF materials successfully modi-fied BC to form a composite material.The maximum weight loss stage temperature of the β-CD-MOF@BC composite material was delayed by 44 ℃ compared to the blank BC material,and the nicotine release in-creased by 5.8 percentage points with a time delay of 1.055 min.The load capacity of the composite was better than that of blank BC materi-al,and it had a certain slow release property.Thermal desorption ofβ-CD-MOF@BC composite materials released up to 20 types of aroma components,which was beneficial for improving the sensory quality of food intake.

heat-not-burn cigarettesnew tobacco sheetsnicotine sustained-releasebacterial cellulose MOF composite material

马科、裴安然、刘文召、尹献忠、杨金初、张婷婷、苏泽宇、徐永明、杨雪鹏

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郑州轻工业大学,河南郑州,450001

河南中烟工业有限责任公司技术中心,河南郑州,450000

加热不燃烧卷烟 新型烟草薄片 烟碱缓释 细菌纤维素MOF复合材料

2024

中国造纸
中国造纸学会 中国制浆造纸研究院

中国造纸

北大核心
影响因子:0.525
ISSN:0254-508X
年,卷(期):2024.43(12)