首页|巯基砷在土水环境-植物体系中迁移转化与健康风险的研究进展

巯基砷在土水环境-植物体系中迁移转化与健康风险的研究进展

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巯基砷是砷物质结构中双键氧(=O)、羟基(—OH)或甲基(—CH3)被双键硫(=S)或巯基(—SH)取代的新型砷化合物,普遍存在于淹水的含硫土壤中,威胁着土壤健康和食品安全.伴随分析方法的进步,对巯基砷在土水环境-植物体系中分布规律和环境行为的研究不断取得新进展.本文对巯基砷的化学形态和分析方法、巯基砷在土水环境中的生物地球化学行为、巯基砷在土水环境-植物体系中的迁移转化与赋存规律、巯基砷在稻米中的赋存和健康风险等4个方面进行了阐述,重点梳理了巯基砷在环境行为中所发生的形态和含量变化情况,并对巯基砷研究的发展趋势进行了展望.
Advances in migration and transformation of thiolated arsenic and its health risks in soil-water environment and plant system
Thiolated arsenic is a new type of arsenic compounds in which=O,—OH or—CH3 are replaced by=S or—SH in the structure of arsenic material.It has been found to be ubiquitous in flooded sulfur-containing soils,threatening soil health and food safety.With the advancement of analytical methods,new progress has been made in the study of the distribution and environmental behaviors of thiolated arsenic in soil-water environment and plant system.This paper reviewed the related research progress in recent years from the following four aspects:1)chemical species and analytical methods of thiolated arsenic;2)biogeochemical behaviors of thiolated arsenic in soil-water environment;3)migration,transformation,and accumulation of thiolated arsenic in soil-water environment and plant system;4)accumulation and health risks of thiolated arsenic m rice grains.This review emphasized the changes in the species and content of thiolated arsenic during environmental processes.Furthermore,the development trend of thiolated arsenic was prospected.

thiolated arsenicsoil-water environmentricebiogeochemical behaviorshealth risks

强震宇、江逸帆、李刚、韩永和、管冬兴

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浙江大学环境与资源学院,浙江 杭州 310058

中国科学院城市环境研究所,福建厦门 361021

福建师范大学环境与资源学院,福建 福州 350117

巯基砷 土水环境 水稻 生物地球化学行为 健康风险

国家自然科学基金项目中央高校基本科研业务费专项资金项目

421771942021QNA6004

2024

浙江大学学报(农业与生命科学版)
浙江大学

浙江大学学报(农业与生命科学版)

CSTPCD北大核心
影响因子:0.725
ISSN:1008-9209
年,卷(期):2024.50(5)