浙江化工2024,Vol.55Issue(1) :27-33.DOI:10.3969/j.issn.1006-4184.2024.01.005

高镍基催化剂催化环戊酮加氢制备环戊醇

Hydrogenation of Cyclopentanone to Cyclopentanol Catalyzed by High Nickel-Based Catalyst

郭昊 彭飞扬 彭秧锡 秦飞 王刚 彭伟才
浙江化工2024,Vol.55Issue(1) :27-33.DOI:10.3969/j.issn.1006-4184.2024.01.005

高镍基催化剂催化环戊酮加氢制备环戊醇

Hydrogenation of Cyclopentanone to Cyclopentanol Catalyzed by High Nickel-Based Catalyst

郭昊 1彭飞扬 1彭秧锡 2秦飞 1王刚 1彭伟才1
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作者信息

  • 1. 湖南人文科技学院, 湖南 娄底 417000
  • 2. 湖南人文科技学院, 湖南 娄底 417000;湖南省精细陶瓷与粉体重点实验室, 湖南 娄底 417000
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摘要

本文以环戊酮为原料,采用镍基催化剂通过固定床加氢工艺制备环戊醇.研究了溶剂、反应温度、氢气压力、环戊酮的含量及进料空速等因素对反应的影响,并对工艺条件进行优化.在5mL催化剂评价装置开展实验,取得最佳工艺条件为:以乙醇作为溶剂,温度为190℃、氢气压力为 1.5 MPa、环戊酮的含量为 15%的乙醇混合液,进料空速为 2.16 h-1.环戊酮的转化率为91.47%,环戊醇的选择性为 97.66%.

Abstract

In this paper,cyclopentanone was used as raw material to prepare cyclopentanol by nickel-based catalyst through fixed bed hydrogenation process.The effects of solvent,reaction temperature,hydrogen pressure,cyclopentanone content and feed space velocity on the reaction were studied,and the process conditions were optimized.Experiments were carried out in a 5 mL catalyst evaluation device.The optimum process conditions were obtained as follows:ethanol was used as solvent,the temperature was 190℃,the hydrogen pressure was 1.5 MPa,ethanol mixture with cyclopentanone content of 15%,and the feed space velocity was 2.16 h-1.The conversion of cyclopentanone was 91.47%,and the selectivity of cyclopentanol was 97.66%.

关键词

镍基催化剂/环戊醇/环戊酮/固定床/乙醇

Key words

nickel-based catalyst/cyclopentanol/cyclopentanone/fixed bed/ethanol

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基金项目

湖南省重点研发计划资助项目(2021GK2015)

出版年

2024
浙江化工
浙江省化工研究院有限公司

浙江化工

影响因子:0.131
ISSN:1006-4184
参考文献量2
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