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苦参碱在梨和土壤中的残留及消解动态

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为探明植物源农药苦参碱在梨及其土壤中的残留和消解情况,该研究采用气相色谱带氮磷检测器(NPD)分析法,在天津和安徽开展了苦参碱在梨和土壤中消解动态规律和残留情况的研究。结果表明,苦参碱在梨和土壤中的最低检测限为 1。36×10-12 g,在梨和土壤中的最低检出浓度分别为 0。01 和 0。004 mg·kg-1。在天津和安徽,苦参碱在梨中的消解半衰期分别为 4。89 和 3。94 d,在土壤中的消解半衰期分别为 4。77 和 5。27 d,其消解均符合消解动态方程。采用高低剂量分别施药 3 和 4 次,施药 7~28 d后,梨和土壤中的最终残留均低于我国农药残留限量标准中的临时最大限量值(MRL)5 mg·kg-1。因此,在规范施药条件下,苦参碱在梨和土壤中属于低残留、易消解农药,在梨上施用膳食摄入风险低,施用相对安全。
Residue and dissipation of matrine in pear and soil
In order to clarify the residue and degradation dynamics of botanical pesticide matrine in pear and soil,gas chromatography with nitrogen phosphorus detector(NPD)was used to analyze the degradation dynamics and residue of marine in pear and soil in Tianjing and Anhui for this study.The results indicated that the limit of detection of matrine in pear and soil was 1.36×10-12 g,and the lowest detected concentrations were 0.01 mg·kg-1 in pear and 0.004 mg·kg-1 in soil,respectively.In Tianjing province,the half-life of matrine in pear and soil were 4.89 and 4.77 d respectively.While,in Anhui,the half-life of matrine in pear and soil were 3.94 and 5.27 d respectively.The degradation rules of matrine in pear and soil in Tianjing and Anhui can fit the degradation dynamic equation.When matrine was applied with low and high dosages for three and four times at an interval of 7 d,the final residue in pear and soil were lower than the temporary maximum limit value(MRL)5 mg·kg-1in national food safety standard-maximum residue limits for pesticides in food after 7-28 d of application.Therefore,matrine is low residue and easily degradation pesticide on pears and soil.Under standard use conditions,there is no dietary risk when it is applied on pears,so it is relatively safe to apply.

matrinepearresiduedegradation dynamic

卢莉娜、沈燕、高美静、仲建锋、卢飞、郑尊涛、张志勇

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省部共建国家重点实验室培育基地-江苏省食品质量安全重点实验室,江苏 南京 210014

江苏省农业科学院 农产品质量安全与营养研究所,江苏 南京 210014

农业农村部农药检定所,北京 100010

苦参碱 残留 消解动态

现代农业产业技术体系建设专项科技部"中医药现代化研究"重点研发专项

CARS-282017YFC1700800

2024

浙江农业科学
浙江省农业科学院,浙江大学

浙江农业科学

影响因子:0.523
ISSN:0528-9017
年,卷(期):2024.65(9)