首页|聚合物纳米复合增黏剂的制备

聚合物纳米复合增黏剂的制备

Preparation and Performance Evaluation of Polymer Nanocomposite Viscosifier

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针对目前常用的钻井液增黏剂在高温高盐下增黏性能较差,无法适用于高温深部储层的问题,以 2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、N,N-二乙基-2-丙烯酰胺(DEAM)、N,N-亚甲基双丙烯酰胺(MBA)和改性纳米SiO2 颗粒(E-np)为原料,通过原位聚合制备了一种高温增稠性能良好的纳米复合材料E-APNC.通过正交实验对合成条件进行了优化,使用傅里叶变换红外光谱(FT-IR)确定了E-APNC的分子结构,考察了E-APNC的增黏性能、抗剪切性能、耐温性能和耐温抗盐性能.通过 24h的静置实验,考察了nps、N-np、和E-np的分散性,E-np具有更好的分散性.研究结果表明,在常温下 1%加量的E-APNC溶液表观黏度达 66 mPa·s,与APNC相比具有良好的增黏性能;加量为 1%、剪切速率为 1021 s-1 的E-APNC溶液黏度可达 60 mPa·s;在 20%NaCl溶液中,200℃老化 16h后,E-APNC溶液的表观黏度保持率达65%.与聚合物APNC和N-APNC相比,E-APNC具有更好的抗剪切性能与耐温抗盐性能.
In response to conventional viscosifiers exhibiting poor performance under high temperature and high salt conditions rendering them ineffective for high-temperature deep reservoirs,this study prepared a novel nanocomposite(E-APNC)via in situ polymerization using 2-acrylamido-2-methylpropanesulfonic acid,N,N diethylacrylamide,N,N methylenebisacrylamide and nano-SiO2 particles(E-np)as raw materials.E-APNC synthetic condition was optimized by orthogonal experimentation,and the molecular structure of E-APNC was evidenced by FT-IR,E-APNC polymer fluid displayed good thickening performance at high temperatures with excellent rheological parameter such as viscosity increase,shear resistance,thermal stability,and salt tolerance.Through the 24 h static experiment,E-np has better dispersibility compared with nps and N-np.At 1%E-APNC,the apparent viscosity at room temperature reached 66 mPa·s,whereas the viscosity shear rate reached 60 mPa·s at high shear rate of 1021 s-1,showcasing the excellent viscosity increasing ability and good anti-shear performance of E-APNC.The apparent viscosity retention rate of the drilling fluid was 65%after aging at 200℃for 16 h under 20%NaCl concentration probing its good temperature and salt resistance performance.Compared with polymer APNC and N-APNC,E-APNC showed strong shear resistance and good temperature resistance,salt resistance.

Composite materialSiO2 modificationViscosifierTemperature and salt tolerant

宋祥先、王本利、仇恒彬、慕熙荣、谢彬强

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长江大学石油工程学院,湖北 武汉 430100

中国石化胜利石油工程有限公司黄河钻井总公司,山东 东营 257513

中石化胜利石油工程有限公司钻井工艺研究院,山东 东营 257000

油气钻采工程湖北省重点实验室,湖北 武汉 430100

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复合材料 SiO2改性 增黏性能 耐温抗盐

2024

钻井液与完井液
中国石油集团渤海钻探工程有限公司 中国石油华北油田公司

钻井液与完井液

CSTPCD北大核心
影响因子:1.079
ISSN:1001-5620
年,卷(期):2024.41(6)