仲恺农业工程学院学报2024,Vol.37Issue(1) :9-15.DOI:10.3969/j.issn.1674-5663.2024.01.002

高性能木质素纳米农药分散剂的制备和性能研究

Preparation and performance investigation of high-performance lignin-based nanopesticide dispersant

于杰瑶 林跃琪 薛淑豪 楼宏铭 庞煜霞
仲恺农业工程学院学报2024,Vol.37Issue(1) :9-15.DOI:10.3969/j.issn.1674-5663.2024.01.002

高性能木质素纳米农药分散剂的制备和性能研究

Preparation and performance investigation of high-performance lignin-based nanopesticide dispersant

于杰瑶 1林跃琪 1薛淑豪 1楼宏铭 1庞煜霞1
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作者信息

  • 1. 华南理工大学化学与化工学院,广东广州 510640
  • 折叠

摘要

木质素磺酸盐是常用农药分散剂,但无法满足纳米农药分散要求.本论文通过磺甲基化结合烷基桥联制备不同分子量和磺化度的木质素样品,探讨了分子量和磺化度对其在纳米农药悬浮剂中分散稳定性能的影响.结果表明:相同磺化度下随着分子量的提高,木质素分散剂的分散稳定性能先提高后降低;要获得最好分散效果,磺化度和分子量需要联动,随着木质素磺化度提高,其适宜分子量应该相应提高.磺化度为1.58 mmol/g、分子量为14 897 Da的木质素样品GCL4-Nano对不同纳米农药品种均有优秀分散稳定性能,制备的纳米农药悬浮剂平均粒径为165~206 nm,悬浮率超过95%,且具有良好润湿性、抗雨水冲刷能力和抗光解性.

Abstract

Dispersants containing lignosulfonate were commonly used in pesticides,but they failed to meet the requirements for nanoparticle pesticide dispersion.Lignin samples with varying molecular weights and degrees of sulfonation were prepared through the process of sulfomethylation combined with alkyl bridging.The influence of molecular weight and degree of sulfonation on their dispersion stability in nanopesticide suspensions was explored.The results indicated that,at the same degree of sulfonation,the dispersion stability of lignin dispersants was initially improved and then decreased with increasing molecu-lar weight.To achieve the best dispersion effect,the sulfonation degree and molecular weight of lignin needed to be coordinated.As the sulfonation degree increased,the appropriate molecular weight should also increase accordingly.GCL4-Nano,with a sulfonation degree of 1.58 mmol/g and a molecular weight of 14 897 Da,was found to exhibit excellent dispersion stability for nanopesticides of different varieties.The nanopesticide suspensions prepared had an average particle size ranging from 165 nm to 206 nm,with a suspension rate exceeding 95%.Additionally,they demonstrated excellent wetting properties,re-sistance to rainwater washing,and photostability.

关键词

木质素/分子量/磺化度/纳米农药/分散剂

Key words

lignin/molecular weight/sulfonation degree/nanopesticide/dispersant

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基金项目

广东省重点领域研发计划(2020B1111380002)

广东省重点领域研发计划(2023B020208002)

广东省现代农业产业技术创新团队专项(2019KJ140)

出版年

2024
仲恺农业工程学院学报
仲恺农业工程学院

仲恺农业工程学院学报

影响因子:0.292
ISSN:1674-5663
被引量1
参考文献量25
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