首页|氢液化装置防固氧累积及安全消除固氧的流程优化

氢液化装置防固氧累积及安全消除固氧的流程优化

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氢液化过程中氧含量超标可能导致固氧累积并导致氢氧爆炸风险.分析了由此引发的爆炸事故,并阐述了预防固氧累积的重要性.综述了近年来防止固氧累积的研究成果,包括使用超纯氢作为原料气、增加固氧洗涤器、将固氧累积调整为固空累积等,这些方法在一定程度上增加了成本或能耗.提出了一种新的解决方案,通过安装两道节流阀来防止固氧累积并安全地消除累积的固氧.通过流程模拟计算,证明了这种优化流程更易获得过冷液氢.该优化流程方案在实际应用中不会增加额外设备和能耗,具有广泛的适用性.
Process Optimization for Preventing Solid Oxygen Accumulation and Safely Eliminating Solid Oxygen in Hydrogen Liquefier
Excessive oxygen content in the process of hydrogen liquefaction will lead to the accumulation of solid oxy-gen and the risk of hydrogen-oxygen explosion.These explosion incidents caused by such accumulations are introduced,and the importance of preventing solid oxygen accumulation is emphasized.The recent research achievements in preventing solid oxygen accumulation are reviewed,including the use of ultrapure hydrogen as feed gas,the addition of solid oxygen scrub-bers,and the adjustment of solid oxygen accumulation to solid air accumulation.These methods may increase costs or ener-gy consumption.A new solution to prevent the accumulation of solid oxygen and safely eliminate it by installing two throttle valves is proposed.Meanwhile,the process simulation validates that supercooled liquid hydrogen may be obtained more easi-ly by the optimized process.The optimized process is suitable for a wide range of hydrogen liquefaction plants without addi-tional equipment or increased energy consumption in practical applications.

hydrogen liquefaction plantsolid oxygen accumulationhydrogen-oxygen explosion

杨坤、熊联友、朱璟琦

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北京中科富海低温科技有限公司,北京 100198

中国科学院理化技术研究所,北京 100190

氢液化装置 固氧累积 氢氧爆炸

国家重点研发计划

2020YFB1506202

2024

真空与低温
中国航天科技集团公司第五研究院510研究所

真空与低温

CSTPCD
影响因子:0.567
ISSN:1006-7086
年,卷(期):2024.30(4)