首页|热脱附-气相色谱质谱联用法分析3种活性炭添加对燃香16种TVOC的吸附作用

热脱附-气相色谱质谱联用法分析3种活性炭添加对燃香16种TVOC的吸附作用

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文中建立了热脱附-气质联用分析法,分析 3 种活性碳对燃香后 16 种TVOC的吸附作用,该分析方法R2>0.9947,检出限为 2.008~11.783 μg/mL,定量限为 8.033~47.131 μg/mL,RSD为 0.67%~2.82%,加标回收率为83.24%~122.91%,满足分析方法的检测控制要求.3 种活性炭在室温下对燃香的 16 种TVOC吸附能力与其比表面积呈现正相关性;在燃烧高温状态下的吸附性能受化学吸附和物理吸附共同影响,甚至在燃后会造成脱附,后期需要搭载与其相反应的氧化物加强化学吸附以达到更好的吸附效果.
Analysis of 3 Activated Carbons Adsorb 16 Kinds of TVOC from Burning Incense by Thermal Desorption-gas Chromatography-mass Spectrometry
A thermal desorption-GC-MS method was established to analyze the adsorption of three activated carbons on 16 TVOC from burning Incense.The linearities of the 16 target TVOCs were good with correlation coefficients greater than0.9947,the method detectiom limits(MDL)of the 16 TVOCs ranged from 2.008 μg/ml to 11.783μg/ml,the quantitative limit(LOQ)ranged from 8.033 μg/ml to 47.131μg/ml.The relative standard deviations(RSDs)of the 16 TVOCs were ranged from 0.67%to 2.82%.The 20 μg/ml and 100μg/ml spiked eagle ranged from 83.24%~122.91%,which meet the detection and control requirements of the analytical method.At room temperature,the adsorption capacity of the 3 activated carbons on 16 kinds of TVOC was positively correlated with its specific surface area.The adsorption properties under the high temperature state were affected by chemical adsorption and physical adsorption,and even cause desorption after combustion.In the later stage,it is necessary to carry the corresponding oxides to strengthen chemical adsorption to achieve better adsorption effect.

Activated carbonsBurning incenseTVOCSpecific surface area

陈萍芸

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永春县产品质量检验所,福建 永春 362600

福建省香产品质量检验中心,福建 永春 362600

国家燃香类产品质量监督检验中心(福建),福建 永春 362600

活性炭 燃香 TVOC 比表面积

国家市场监督管理总局科技项目

2021MK051

2023

市场监管与质量技术研究
福建省标准化研究院

市场监管与质量技术研究

影响因子:0.299
ISSN:2097-0870
年,卷(期):2023.(6)
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