中南大学学报(英文版)2023,Vol.30Issue(12) :3881-3896.DOI:10.1007/s11771-023-5510-6

Cu(Ⅱ)高效吸附剂氧化石墨烯/聚亚胺二乙酸树脂的制备

Preparation of graphene oxide/polyiminodiacetic acid resin as a high-performance adsorbent for Cu(Ⅱ)

马鑫 段广宇 黄家琦 杨佳 曹占芳 王帅
中南大学学报(英文版)2023,Vol.30Issue(12) :3881-3896.DOI:10.1007/s11771-023-5510-6

Cu(Ⅱ)高效吸附剂氧化石墨烯/聚亚胺二乙酸树脂的制备

Preparation of graphene oxide/polyiminodiacetic acid resin as a high-performance adsorbent for Cu(Ⅱ)

马鑫 1段广宇 1黄家琦 1杨佳 1曹占芳 1王帅1
扫码查看

作者信息

  • 1. College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China;Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources,Central South University,Changsha 410083,China
  • 折叠

摘要

重金属污染已成为水生生态系统面临的巨大挑战.本文采用Amberlite IRC 748树脂对氧化石墨烯(GO)进行改性,制备了一种多功能复合吸附材料(IRC 748-GO).通过静态吸附和动态吸附实验考察了IRC 748-GO复合材料对Cu2+离子的吸附行为,结果表明该吸附过程符合准二级动力学模型和Langmuir模型,Cu2+的饱和吸附量达到127.22 mg/g,IRC 748-GO复合材料对Cu2+的吸附能力强于氧化石墨烯.采用FT-IR、SEM、XPS和吸附等温线测定分析了吸附机理,结果表明IRC 748-GO复合材料中的羧基能有效螯合Cu2+离子.IRC 748-GO复合材料具有比表面积大、稳定性好、吸附能力强等特点,可用于重金属废水处理.

Abstract

Heavy metal-contaminated water has become a great challenge for aquatic ecosystems.Herein,a versatile composite(IRC 748-GO)adsorbent was prepared by modifying graphene oxide(GO)with Amberlite IRC 748 resin.The batch and dynamic adsorption experiments of Cu2+ on the IRC 748-GO composite were conducted,and the results showed that the novel adsorbents have a high adsorption capacity compared to the pristine GO.The adsorption process was consistent with the pseudo-second-order kinetic model and the equilibrium data were well fitted to the Langmuir isotherm model,and the maximum uptake of Cu2+ was 127.22 mg/g.The adsorption mechanism was investigated using FT-IR,SEM,XPS,and adsorption isotherms,which revealed that the carboxyl groups in IRC 748-GO composite could effectively chelate Cu2+.Overall,the IRC 748-GO composite exhibited important advantages such as great specific surface area and stability,as well as high adsorption capacity,which provides broad application prospects for efficiently remediating wastewater containing heavy metals.

关键词

氧化石墨烯/Amberlite/IRC/748树脂/铜(Ⅱ)/吸附/废水处理

Key words

graphene oxide/Amberlite IRC 748 resin/copper(Ⅱ)/adsorption/wastewater treatment

引用本文复制引用

基金项目

National Science and Technology Major Project of China(2013ZX07504)

Natural Science Foundation of Hunan Province,China(2018JJ2484)

出版年

2023
中南大学学报(英文版)
中南大学

中南大学学报(英文版)

CSTPCDCSCDEI
影响因子:0.47
ISSN:2095-2899
参考文献量8
段落导航相关论文