首页|用于钎焊C/C复合材料的稀土改性还原氧化石墨烯增强AgCuTi复合钎料

用于钎焊C/C复合材料的稀土改性还原氧化石墨烯增强AgCuTi复合钎料

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为了解决钎焊接头中脆性化合物的形成问题,我们设计了一种创新性的稀土改性还原氧化石墨烯增强AgCuTi复合钎料,进而获得了以Ag-Cu共晶为主要组织且脆性化合物生成量合适的钎焊接头。对比分析了有无稀土Ce改性的复合钎料的成分和显微组织,结果表明,经Ce改性后的还原氧化石墨烯在钎料中更加均匀分散。比较了分别采用有无Ce改性的钎料钎焊C/C复合材料-C/C复合材料接头的界面微观结构,并研究了石墨烯含量对接头组织和性能的影响。结果表明,由于经Ce改性的钎料中的还原氧化石墨烯分散性更好,从而细化了焊缝组织,且物相分布更均匀,使得接头的剪切强度明显提高。当石墨烯含量为 0。5 wt。%时,使用Ce改性的钎料所得钎焊接头的平均剪切强度最高,为31。82 MPa,提高了50%。
Rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler for brazing C/C composites
In order to solve the formation of brittle compounds in brazed joints,an innovative rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler was designed to achieve brazed joints with Ag-Cu eutectic as the main organization almost free of brittle compounds,and at the same time,the dispersion of graphene in the joint interfaces was improved.Microanalysis and discussion of the brazing fillers with and without Ce modification showed that the Ce modified reduced graphene oxide was more uniformly dispersed in the brazing fillers.The interfacial microstructures of C/C composites-C/C composites joints with and without Ce modified brazing fillers were compared,and the effect of graphene content on the organization and properties of the joints was investigated.The results showed that the shear strength of the joints was significantly enhanced by using Ce modified brazing fillers.When the graphene content was 0.5 wt.%,the average shear strength of the brazed joints obtained by using Ce modified brazing fillers was 31.82 MPa,increased by 50%.

rare earth modificationreduced graphene oxidecomposite fillerC/C compositesbrazing

吴靓、李月、陈锦微、张汭、张乾坤、肖逸锋

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School of Mechanical Engineering and Mechanics,Xiangtan University,Xiangtan 411105,China

Key Laboratory of Welding Robot and Application Technology of Hunan Province,Xiangtan 411105,China

Welding Automation Equipment Engineering Research Center of Hunan Province,Xiangtan 411105,China

稀土改性 还原氧化石墨烯 复合钎料 C/C复合材料 钎焊

2024

中南大学学报(英文版)
中南大学

中南大学学报(英文版)

CSTPCDEI
影响因子:0.47
ISSN:2095-2899
年,卷(期):2024.31(5)
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