中南大学学报(英文版)2024,Vol.31Issue(10) :3612-3627.DOI:10.1007/s11771-024-5806-1

阴极保护对海洋潮汐环境中X80钢Desulfovibrio desulfuricans腐蚀的影响

Effect of cathode protection on Desulfovibrio desulfuricans corrosion of X80 steel in a marine tidal environment

周小包 王子豪 欧阳泽伦 苏慧 王勇 李智 吴堂清
中南大学学报(英文版)2024,Vol.31Issue(10) :3612-3627.DOI:10.1007/s11771-024-5806-1

阴极保护对海洋潮汐环境中X80钢Desulfovibrio desulfuricans腐蚀的影响

Effect of cathode protection on Desulfovibrio desulfuricans corrosion of X80 steel in a marine tidal environment

周小包 1王子豪 1欧阳泽伦 1苏慧 1王勇 2李智 1吴堂清1
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作者信息

  • 1. School of Materials Science and Engineering,Xiangtan University,Xiangtan 411105,China
  • 2. Singapore Centre for 3D Printing,Nanyang Technological University,50 Nanyang Avenue,Singapore 639798,Singapore;School of Materials Science and Engineering,Nanyang Technological University,50 Nanyang Avenue,Singapore 639798,Singapore
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摘要

本文利用失重分析、电化学测量、拉曼光谱和超景深三维显微镜等分析测试技术系统研究了海洋潮汐环境中锌牺牲阳极(zinc sacrificial anode,Zn-SA)阴极保护对X80钢的脱硫脱硫弧菌(Desulfovibro desulfuricans,D.desulfuricans)腐蚀的影响.在海洋潮汐环境中,D.desulfuricans细胞活性较高,X80钢发生了明显的D.desulfuricans腐蚀,腐蚀以局部腐蚀为主.Zn-SA阴极保护作用下,浮游和固着D.desulfuricans的活性显著降低,腐蚀产物中钙质沉积物的含量逐渐增加,腐蚀产物电阻Rf值逐渐上升.Zn-SA阴极保护显著地抑制了 X80钢D.desulfuricans腐蚀,但是这种抑制作用会随着X80钢在潮汐环境中的垂直高度的升高而降低.

Abstract

The study systematically investigated the impact of zinc sacrificial anode(Zn-SA)cathode protection on the corrosion of X80 steel caused by Desulfovibrio desulfuricans(D.desulfuricans)in a marine tidal environment.Utilizing weight-loss analysis,electrochemical measurements,Raman spectroscopy,and 3D morphology microscopy,the research unveiled significant findings.Unprotected steel suffered pronounced localized corrosion in the presence of D.desulfuricans in the marine tidal environment.However,the implementation of Zn-SA cathode protection notably reduced the activity of both planktonic and sessile D.desulfuricans cells.Over time,the accumulation of calcareous deposits within the corrosion products increased,as evidenced by a rise in the resistance of the corrosion produt film(Rf).Remarkably,Zn-SA cathode protection demonstrated substantial inhibition of the steel's corrosion rate,albeit exhibiting reduced efficiency as the vertical height of the steel within the tidal environment increased.

关键词

X80管线钢/微生物腐蚀/海洋潮汐腐蚀/Desulfovibro/desulfuricans/阴极保护

Key words

X80 pipeline steel/microbial corrosion/marine tidal corrosion/Desulfovibro desulfuricans/cathode protection

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出版年

2024
中南大学学报(英文版)
中南大学

中南大学学报(英文版)

CSTPCDCSCDEI
影响因子:0.47
ISSN:2095-2899
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