首页|Ti-Mo-V复合添加对船用10Ni5CrMoV钢组织和性能的影响

Ti-Mo-V复合添加对船用10Ni5CrMoV钢组织和性能的影响

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系统研究了 Ti-Mo-V复合添加对船用10Ni5CrMoV钢中析出相演变及其强韧性机制的影响.复合添加Ti-Mo-V能够以Ti(C)→V→Mo的顺序形成TiC为核、Mo-V为壳的TixMoyVzC碳化物.当Ti的质量分数为0~0.1 wt.%时,等效晶粒尺寸从1.70 μm减小到0.91 μm,马氏体板条平均宽度从144 nm减小到103 nm,析出相的等效直径从88 nm减小到59 nm.由于纳米析出相增强了对晶界和位错的钉扎作用,提高了析出和位错强化的贡献,使得试样的屈服强度从815 MPa提高到876 MPa.等效晶粒尺寸的减小和大角度晶界取向占比的增加,阻碍了裂纹的萌生和扩展,使得试样的DBTT值从-103 ℃下降到-116 ℃.当Ti的质量分数为0.05%时,试样的强度和低温韧性能够协同提高,这也为探索优良强度和低温韧性匹配的船用10Ni5CrMoV钢的提供了理论依据和实验参考.
Effect of Ti-Mo-V composite addition on microstructure and mechanical properties of marine 10Ni5CrMoV steel
The effects of Ti-Mo-V composite addition on the evolution of precipitates in marine 10Ni5CrMoV steel and the corresponding strength and toughness mechanisms were systematically investigated.Ti-Mo-V composite addition can form the TixMoyVzC carbide with TiC as core and Mo-V as shell in the order of Ti(C)→V→Mo.The yield strength of the specimens is increased from 815 MPa to 876 MPa due to the nanoscale precipitates enhancing the pinning effect on grain boundaries and dislocations,and the contribution of precipitation and dislocation strengthening is increased.The decrease of ductile-brittle transition temperature from-103 to-116 ℃ is attributed to the decrease in equivalent grain size and the increase of high-angle grain boundary misorientation,which hinders the initiation and propagation of cracks.When the mass fraction of Ti is 0.05%,the strength and cryogenic toughness can be improved synergistically,which also provides a theoretical basis and experimental reference for exploring the more excellent combination of strength and cryogenic toughness of marine 10Ni5CrMoV steel.

10Ni5CrMoV steelTi-Mo-V composition additionductile-brittle transition temperatureTixMo VCmechanical properties

邹涛、董艳伍、姜周华、王琪、王永、彭飞

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School of Metallurgy,Northeastern University,Shenyang 110819,China

Key Laboratory of Rolling and Automation,Northeastern University,Shenyang 110819,China

Key Laboratory for Ecological Metallurgy of Multimetallic Ores(Ministry of Education),Northeastern University,Shenyang 110819,China

10Ni5CrMoV钢 Ti-Mo-V复合添加 韧脆转变温度 TixMoyVzC 机械性能

2024

中南大学学报(英文版)
中南大学

中南大学学报(英文版)

CSTPCDEI
影响因子:0.47
ISSN:2095-2899
年,卷(期):2024.31(10)