中南大学学报(英文版)2024,Vol.31Issue(10) :3628-3645.DOI:10.1007/s11771-024-5795-0

Ti-Mo-V复合添加对船用10Ni5CrMoV钢组织和性能的影响

Effect of Ti-Mo-V composite addition on microstructure and mechanical properties of marine 10Ni5CrMoV steel

邹涛 董艳伍 姜周华 王琪 王永 彭飞
中南大学学报(英文版)2024,Vol.31Issue(10) :3628-3645.DOI:10.1007/s11771-024-5795-0

Ti-Mo-V复合添加对船用10Ni5CrMoV钢组织和性能的影响

Effect of Ti-Mo-V composite addition on microstructure and mechanical properties of marine 10Ni5CrMoV steel

邹涛 1董艳伍 2姜周华 2王琪 1王永 1彭飞1
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作者信息

  • 1. School of Metallurgy,Northeastern University,Shenyang 110819,China
  • 2. School of Metallurgy,Northeastern University,Shenyang 110819,China;Key Laboratory of Rolling and Automation,Northeastern University,Shenyang 110819,China;Key Laboratory for Ecological Metallurgy of Multimetallic Ores(Ministry of Education),Northeastern University,Shenyang 110819,China
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摘要

系统研究了 Ti-Mo-V复合添加对船用10Ni5CrMoV钢中析出相演变及其强韧性机制的影响.复合添加Ti-Mo-V能够以Ti(C)→V→Mo的顺序形成TiC为核、Mo-V为壳的TixMoyVzC碳化物.当Ti的质量分数为0~0.1 wt.%时,等效晶粒尺寸从1.70 μm减小到0.91 μm,马氏体板条平均宽度从144 nm减小到103 nm,析出相的等效直径从88 nm减小到59 nm.由于纳米析出相增强了对晶界和位错的钉扎作用,提高了析出和位错强化的贡献,使得试样的屈服强度从815 MPa提高到876 MPa.等效晶粒尺寸的减小和大角度晶界取向占比的增加,阻碍了裂纹的萌生和扩展,使得试样的DBTT值从-103 ℃下降到-116 ℃.当Ti的质量分数为0.05%时,试样的强度和低温韧性能够协同提高,这也为探索优良强度和低温韧性匹配的船用10Ni5CrMoV钢的提供了理论依据和实验参考.

Abstract

The effects of Ti-Mo-V composite addition on the evolution of precipitates in marine 10Ni5CrMoV steel and the corresponding strength and toughness mechanisms were systematically investigated.Ti-Mo-V composite addition can form the TixMoyVzC carbide with TiC as core and Mo-V as shell in the order of Ti(C)→V→Mo.The yield strength of the specimens is increased from 815 MPa to 876 MPa due to the nanoscale precipitates enhancing the pinning effect on grain boundaries and dislocations,and the contribution of precipitation and dislocation strengthening is increased.The decrease of ductile-brittle transition temperature from-103 to-116 ℃ is attributed to the decrease in equivalent grain size and the increase of high-angle grain boundary misorientation,which hinders the initiation and propagation of cracks.When the mass fraction of Ti is 0.05%,the strength and cryogenic toughness can be improved synergistically,which also provides a theoretical basis and experimental reference for exploring the more excellent combination of strength and cryogenic toughness of marine 10Ni5CrMoV steel.

关键词

10Ni5CrMoV钢/Ti-Mo-V复合添加/韧脆转变温度/TixMoyVzC/机械性能

Key words

10Ni5CrMoV steel/Ti-Mo-V composition addition/ductile-brittle transition temperature/TixMo VC/mechanical properties

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出版年

2024
中南大学学报(英文版)
中南大学

中南大学学报(英文版)

CSTPCDEI
影响因子:0.47
ISSN:2095-2899
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