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磨矿对矿物表面性质和矿浆溶液化学性质的影响研究进展

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磨矿是一个高能耗的过程,提高磨矿效率、降低磨矿能耗是当前的研究热点。磨矿也是一个复杂的物理、化学过程,会改变矿物的表面性质和矿浆溶液化学性质,进而会对矿物的浮选行为产生显著影响。首先,分析了磨机类型、介质、方式对矿物表面性质的影响;其次,总结了常见助磨剂在磨矿过程中的应用,分析了助磨剂分子结构与其助磨性能的关系;最后,总结了磨矿过程对矿浆溶液化学环境及流变性的影响。研究结果表明:改变磨矿条件及环境(磨矿方式、磨矿介质材质及形状、添加助磨剂等)可以强化矿物表面活性位点、粗糙度、疏水性等性质的差异,并且优化矿浆溶解组分,调节矿浆流变性,实现选择性磨矿。在磨矿阶段添加适宜助磨剂,可以优化磨矿产品粒级分布,提升磨矿效率,同时,助磨剂可以与浮选药剂形成协同作用,改善矿物的可浮性。目前,助磨剂的作用机制及对后续矿物浮选体系的影响还有待深入研究。未来应从调控磨矿过程中矿物表面性质的差异、改变矿浆溶解组分、提升矿浆的分散性与流动性入手,开发高选择性的助磨剂,强化矿物浮选分离。
Research progress of effect of grinding on surface properties of minerals and chemical properties of slurry solution
Grinding is a high energy-consuming process,and improving the grinding efficiency and reducing the energy consumption of grinding are the current research hotspots. Grinding as well as a complex physical and chemical process will change the surface properties of minerals and the chemical properties of the slurry solution,which in turn will have a significant impact on the flotation behavior of minerals. Firstly,the effects of mill type,media and mode on the surface properties of minerals were analyzed. Secondly,the applications of common grinding aids in the grinding process were summarized,and the relationship between the molecular structure of grinding aids and their grinding performance was analyzed. Finally,the effects of the grinding process on the chemical environment of the slurry solution and the rheological properties were summarized. The results show that changing the grinding conditions and environment (grinding method,materials and shape of grinding media,addition of grinding aids,etc.) can enhance the differences in the properties of mineral surface active sites,roughness,hydrophobicity,etc.,optimize the dissolved components of the slurry,regulate the rheology of the slurry,and achieve selective grinding. Adding suitable grinding aids in the grinding stage can optimize the particle size distribution of the grinding products and improve the grinding efficiency. At the same time,the grinding aids can form a synergistic effect with the flotation chemicals to improve the floatability of minerals. At present,the role of grinding aids and the influence of the subsequent mineral flotation system need be studied in depth. In the future,we should develop highly selective grinding aids to enhance the separation of minerals flotation by regulating the difference of mineral surface properties during the grinding process,changing the dissolved components of the slurry,and improving the dispersion and fluidity of the slurry.

grinding processflotation behaviormineral surface propertiesslurry solution chemical propertiesregulatory mechanisms

毛勇、刘文刚、刘文宝、王泽红、郑杰、沈岩柏、赵强

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东北大学资源与土木工程学院,辽宁沈阳,110819

贵州科学院,贵州贵阳,550001

磨矿过程 浮选行为 矿物表面性质 矿浆溶液化学性质 调控机制

2024

中南大学学报(自然科学版)
中南大学

中南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.938
ISSN:1672-7207
年,卷(期):2024.55(11)