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四川某高品位磁铁精矿工艺矿物学特征

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超纯铁精矿(TFe质量分数≥72。0%)广泛用于制备高性能铁基材料。本文以四川某高品位磁铁精矿为研究对象,采用化学分析、X荧光光谱分析(XRF)、激光粒度测试、光学显微镜、扫描电子显微镜-X射线能谱(SEM-EDS)和矿物解离分析仪(MLA)等分析测试手段,对该矿样的化学成分、矿物组成、矿物嵌布特征及其连生关系、矿物解离度、矿物类质同象取代等进行研究。研究结果表明:在磁铁精矿中,TFe品位为69。49%,Al2O3和SiO2质量分数分别为0。85%、1。95%;主要含铁矿物为磁铁矿,其质量分数达到94。69%;次要含铁矿物为赤褐铁矿、菱铁矿、钛铁矿以及磁黄铁矿;磁铁矿多呈半自形或不规则粒状产出,磁铁矿整体嵌布粒度较大,变化范围大多为0。02~0。30 mm,大部分呈单体产出,其单体解离度为97。17%;脉石矿物主要为石英、绿泥石、云母、磁黄铁矿,其整体嵌布粒度较大且解离度低,在后续选矿流程中必须进行磨矿作业使其与磁铁矿解离;磁黄铁矿性质与磁铁矿性质接近,分离难度较大,磁黄铁矿中的S元素对精矿品质产生不利影响;磁铁矿中存在Fe、Al类质同象,Al元素难以采用常规的物理分选脱除;磁铁矿中Fe质量分数为72。09%,理论上具有制备超纯铁精矿的条件。
Mineralogical characteristics of a high-grade magnetite concentrate in Sichuan Province
Ultra-pure iron concentrate(w(TFe)≥72.0%) is widely used in the preparation of high-performance iron-based materials. Different analytical methods such as chemical analysis,X-ray fluorescence(XRF) analysis,laser particle size analysis,optical microscopy,scanning electron microscopy with X-ray energy dispersive spectroscopy(SEM-EDS) and mineral liberation analysis(MLA) were used to study the sample's chemical composition,mineral composition,mineral embedding characteristics and intergrowth relationships,mineral liberation degree and mineral isomorphous substitution. The results show that the TFe grade of the magnetite concentrate is 69.49%,with Al2O3 and SiO2 contents of 0.85% and 1.95%,respectively. The primary iron-bearing mineral is magnetite,accounting for 94.69%,while the secondary iron-bearing minerals include hematite,siderite,ilmenite and pyrrhotite. Magnetite mainly occurs in subhedral or irregular granular forms,with a coarse grain size ranging from 0.02 mm to 0.30 mm,mostly as monomers with a liberation degree of 97.17%. Gangue minerals,primarily quartz,chlorite,mica and pyrrhotite have coarse grain sizes and low liberation degrees,requiring grinding in subsequent beneficiation. Pyrrhotite,which is similar in nature to magnetite,is difficult to separate,and its sulfur content negatively affects concentrate quality. Additionally,Fe-Al isomorphous substitution in magnetite makes Al difficult to remove by conventional physical separation methods. Magnetite contains 72.09% Fe,theoretically meeting the conditions for producing ultra-pure iron concentrate.

magnetiteultra-pure iron concentrateprocess mineralogydisseminated characteristicliberation degree

戴川、何浩、陈攀、宋林、唐鸿鹄、刘宏强、孙伟

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中南大学资源加工与生物工程学院,湖南长沙,410083

四川省川威集团矿业总公司,四川成都,610100

四川大学材料科学与工程学院,四川成都,610065

四川阿坝矿业有限公司,四川阿坝,623000

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磁铁矿 超纯铁精矿 工艺矿物学 嵌布特征 解离度

2024

中南大学学报(自然科学版)
中南大学

中南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.938
ISSN:1672-7207
年,卷(期):2024.55(11)